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Acta Cryst. (2009). E65, m1050  [ doi:10.1107/S1600536809030700 ]

Tris(dibenzoylmethanido-[kappa]2O,O')[(6S,8S)-(+)-7,7-dimethyl-3-(2-pyridyl)-5,6,7,8-tetrahydro-6,8-methanoisoquinoline-[kappa]2N,N']gadolinium(III)

X.-L. Li and L.-F. He

Abstract: In the title compound, [Gd(C15H11O2)3(C17H18N2)], the GdIII atom is coordinated by six O atoms from three [beta]-diketonate ligands and two N atoms from a chiral ligand LS,S-(+)-7,7-dimethyl-3-(2-pyridyl)-5,6,7,8-tetrahydro-6,8-methanoisoquinoline, in a coordination geometry best described as distorted square-antiprismatic.

Online 8 August 2009


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