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Acta Cryst. (2009). E65, m1114 [ doi:10.1107/S1600536809032516 ]
![[mu]](/logos/entities/mu_rmgif.gif)
-oxido-bis[(4-formyl-2-methoxyphenolato-![[kappa]](/logos/entities/kappa_rmgif.gif)
O1)oxido(1,10-phenanthroline-2N,N')vanadium(V)]Abstract: The title complex, [V2(C8H7O3)2O4(C12H8N2)2], is a centrosymmetric dimer formed by two VV complex units bridged by two 2-oxido groups. The VV atom is six-coordinated by three oxide O atoms, one O atom from a vanillinate ligand and two N atoms from a 1,10-phenanthroline ligand in a significantly distorted octahedral geometry. In the crystal structure, weak intermolecular C-H
O hydrogen bonds connect the molecules into a three-dimensional network.
Online 22 August 2009
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