Acta Cryst. (2009). E65, m1059  [ doi:10.1107/S1600536809029262 ]

cis-Bis[1-allyl-3-(2-pyridyl-N)thioureato-S]palladium(II)

S. Orysyk, V. Bon and V. Pekhnyo

Abstract: Yellow plate-like shaped crystals of the title compound, [Pd(C₉H₁₀N₃S)₂], were obtained by ligand-exchange reaction between palladium(II) acetylacetonate and the corresponding organic reagent at room temperature. The Pd^II atom shows a slightly distorted square-planar coordination geometry consisting of two ligand molecules in a cis conformation that bind in their thiolic tautomeric form. Weak intermolecular PdH interactions with Pd-H distances of 3.328 (2) Å were observed in the crystal structure. The three-dimensional network of the crystal structure is realized by weak intermolecular C-HN, N-HN and C-HS hydrogen bonds.

Online 12 August 2009

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