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Acta Cryst. (2009). E65, m1075  [ doi:10.1107/S1600536809031560 ]

(Methoxo-[kappa]O)oxidobis(quinolin-8-olato-[kappa]2N,O)vanadium(V)

Z. Guo, L. Li, C. Wang, T. Xu and J. Li

Abstract: In the title complex, [V(C9H6NO)2(CH3O)O], the central VV atom is coordinated by the O atoms from the oxido and methoxo ligands and the N and O atoms of two bis-chelating quinolin-8-olate ligands, forming a distorted octahedral environment. In the crystal structure, weak intermolecular C-H...O hydrogen bonds connect molecules into centrosymmetric dimers which are, in turn, linked by weak C-H...[pi] interactions into chains along the b axis.

Online 15 August 2009


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