[HTML version][PDF version][CIF][3d view][Structure Factors][Supplementary Material][CIF check Report][Issue contents]  [Open access]

[Contents scheme]

Acta Cryst. (2009). E65, m1152-m1153  [ doi:10.1107/S1600536809033947 ]

Poly[[diaquahemi-[mu]4-oxalato-[mu]2-oxalato-praseodymium(III)] monohydrate]

T.-H. Yang, Q. Chen, W. Zhuang, Z. Wang and B.-Y. Yue

Abstract: In the title complex, {[Pr(C2O4)1.5(H2O)2]·H2O}n, the PrIII ion, which lies on a crystallographic inversion centre, is coordinated by seven O atoms from four oxalate ligands and two O atoms from two water ligands; further Pr-O coordination from tetradentate oxalate ligands forms a three-dimensional structure. The compound crystallized as a monohydrate, the water molecule occupying space in small voids and being secured by O-H...O hydrogen bonding as an acceptor from ligand water H atoms and as a donor to oxalate O-acceptor sites.

Online 29 August 2009


Copyright © International Union of Crystallography
IUCr Webmaster