Acta Cryst. (2009). E65, m1094  [ doi:10.1107/S1600536809031626 ]

Difluoridodioxido(1,10-phenanthroline)molybdenum(VI)

W. Wang, Y. Zhang, X. Jin and X. Du

Abstract: The title compound, [MoF₂O₂(C₁₂H₈N₂)], has non-crystallographic mirror symmetry. The Mo^VI atom shows a distorted octahedral environment, with the phenanthroline N atoms and the two oxide groups forming the equatorial plane and the F atoms occupying the apical positions. Weak C-HO and C-HF hydrogen-bonding contacts and - interactions [centroid-centroid distance = 3.662 (1) Å] connect the complex molecules into a three-dimensional supramolecular framework.

Online 19 August 2009

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