(1,10-Phenanthroline-κ2N,N′)(triphenyl­phosphine-κP)silver(I) trifluoro­methane­sulfonate

Wu, J.-Q.; Jin, Q.-H.; Hu, K.-Y.; Zhang, C.-L.

doi:10.1107/S1600536809032097

Volume 65
Part 9
Pages m1096-m1097
September 2009

Received 17 June 2009
Accepted 13 August 2009
Online 19 August 2009

Key indicators
Single-crystal X-ray study
T = 293 K
Mean (C-C) = 0.005 Å
R = 0.042
wR = 0.133
Data-to-parameter ratio = 25.1
Details

(1,10-Phenanthroline-²N,N')(triphenylphosphine-P)silver(I) trifluoromethanesulfonate

Jie-Qiang Wu,^a Qiong-Hua Jin,^a ^* Ke-Yi Hu ^a and Cun-Lin Zhang ^b

^aDepartment of Chemistry, Capital Normal University, Beijing 100048, People's Republic of China, and ^bDepartment of Physics, Capital Normal University, Beijing 100048, People's Republic of China
Correspondence e-mail: jinqh204@163.com

The structure of the title complex, [Ag(C₁₂H₈N₂)(C₁₈H₁₅P)]CF₃SO₃, is based on a distorted trigonal-planar N₂P coordination of the Ag^I ion, provided by two N atoms of the bidentate phenanthroline ligand and one P atom of the triphenylphosphine ligand. The phenanthroline ligand and one phenyl ring of the triphenylphosphine ligand almost lie in one plane (maximum deviation = 0.014 Å from the best planes). The crystal structure may be stabilized by an intermolecular C-HO hydrogen bond between the phenanthroline ligand and the O atom of the trifluoromethanesulfonate anion.

Related literature

For related structures, see: Di Nicola et al. (2007); Jin et al. (1999, 2009); Effendy et al. (2007a,b); Awaleh et al. (2005a,b); Pettinari et al. (2007). For general background, see: Howells & Mccown (1977); Bowmaker et al. (2005); Lawrance (1986).

Experimental

Crystal data

[Ag(C₁₂H₈N₂)(C₁₈H₁₅P)]CF₃SO₃
M_r = 699.42
Triclinic, $[P \overline 1]$
a = 10.9832 (2) Å
b = 11.7533 (2) Å
c = 12.2642 (3) Å
= 77.711 (1)°
= 76.183 (1)°
= 73.440 (1)°
V = 1455.66 (5) Å³
Z = 2
Mo K radiation
= 0.87 mm^-1
T = 293 K
0.4 × 0.3 × 0.2 mm

Data collection

Bruker SMART CCD area-detector diffractometer
Absorption correction: multi-scan (SADABS; Bruker, 2007) T_min = 0.735, T_max = 0.832
18629 measured reflections
9515 independent reflections
6777 reflections with I > 2(I)
R_int = 0.021

Refinement

R[F² > 2(F²)] = 0.042
wR(F²) = 0.133
S = 1.00
9515 reflections
379 parameters
H-atom parameters constrained
_max = 0.59 e Å^-3
_min = -0.66 e Å^-3

Table 1
Selected geometric parameters (Å, °)

Ag1-N2	2.2798 (18)
Ag1-N1	2.292 (2)
Ag1-P1	2.3469 (5)

N2-Ag1-N1	73.53 (8)
N2-Ag1-P1	147.77 (6)
N1-Ag1-P1	138.03 (6)

Table 2
Hydrogen-bond geometry (Å, °)

D-HA	D-H	HA	DA	D-HA
C20-H16O2	0.93	2.36	3.285 (6)	173

Data collection: SMART (Bruker, 2007); cell refinement: SAINT-Plus (Bruker, 2007); data reduction: SAINT-Plus; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL.

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: WM2241 ).

Acknowledgements

This work was supported by the National Science Foundation of China (grant No. 20871085), the Committee of Education of Beijing Foundation of China (grant No. KM200610028006), the Project sponsored by SRF for ROCS and SEM, the subsidy of Beijing Personnel Bureau, the National Keystone Basic Research Program (973 Program under grant Nos. 2007CB310408, No. 2006CB302901), the State Key Laboratory of Functional Materials for Informatics and the Shanghai Institute of Microsystems and Information Technology, Chinese Academy of Sciences.

References

Awaleh, M. O., Badia, A. & Brisse, F. (2005a). Inorg. Chem. 44, 7833-7845.
Awaleh, M. O., Badia, A. & Brisse, F. (2005b). Cryst. Growth Des. 5, 1897-1906.
Bowmaker, G. A., Effendy, Marfuah, S., Skelton, B. W. & White, A. H. (2005). Inorg. Chim. Acta, 358, 4371-4388.
Bruker (2007). SMART, SAINT-Plus and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
Di Nicola, C., Effendy, Marchetti, F., Pettinari, C., Skelton, B. W. & White, A. H. (2007). Inorg. Chim. Acta, 360, 1433-1450.
Effendy, Marchetti, F., Pettinari, C., Pettinari, R., Skelton, B. W. & White, A. H. (2007b). Inorg. Chim. Acta, 360, 1451-1465.
Effendy, Marchetti, F., Pettinari, C., Skelton, B. W. & White, A. H. (2007a). Inorg. Chim. Acta, 360, 1424-1432.
Howells, R. D. & Mccown, J. D. (1977). Chem. Rev. 77, 19-92.
Jin, Q. H., Hu, K. Y. S. L. L., Wang, R., Zuo, X., Zhang, C. L. & Lu, X. M. (2009). Polyhedron, doi: 10.1016/j.poly.2009.06.036.
Jin, Q. H., Xin, X. L., Zhu, F. J. & Li, Y. (1999). Z. Kristallogr. New Cryst. Struct. 214, 503-504.
Lawrance, G. A. (1986). Chem. Rev. 86, 17-33.
Pettinari, C., Ngoune, J., Skelton, B. W. & White, A. H. (2007). Inorg. Chem. Commun. 10, 329-331.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.

metal-organic compounds

(1,10-Phenanthroline-2N,N')(triphenylphosphine-P)silver(I) trifluoromethanesulfonate