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Volume 65 
Part 9 
Pages m1096-m1097  
September 2009  

Received 17 June 2009
Accepted 13 August 2009
Online 19 August 2009

Key indicators
Single-crystal X-ray study
T = 293 K
Mean [sigma](C-C) = 0.005 Å
R = 0.042
wR = 0.133
Data-to-parameter ratio = 25.1
Details
Open access

(1,10-Phenanthroline-[kappa]2N,N')(triphenylphosphine-[kappa]P)silver(I) trifluoromethanesulfonate

aDepartment of Chemistry, Capital Normal University, Beijing 100048, People's Republic of China, and bDepartment of Physics, Capital Normal University, Beijing 100048, People's Republic of China
Correspondence e-mail: jinqh204@163.com

The structure of the title complex, [Ag(C12H8N2)(C18H15P)]CF3SO3, is based on a distorted trigonal-planar N2P coordination of the AgI ion, provided by two N atoms of the bidentate phenanthroline ligand and one P atom of the triphenylphosphine ligand. The phenanthroline ligand and one phenyl ring of the triphenylphosphine ligand almost lie in one plane (maximum deviation = 0.014 Å from the best planes). The crystal structure may be stabilized by an intermolecular C-H...O hydrogen bond between the phenanthroline ligand and the O atom of the trifluoromethanesulfonate anion.

Related literature

For related structures, see: Di Nicola et al. (2007[Di Nicola, C., Effendy, Marchetti, F., Pettinari, C., Skelton, B. W. & White, A. H. (2007). Inorg. Chim. Acta, 360, 1433-1450.]); Jin et al. (1999[Jin, Q. H., Xin, X. L., Zhu, F. J. & Li, Y. (1999). Z. Kristallogr. New Cryst. Struct. 214, 503-504.], 2009[Jin, Q. H., Hu, K. Y. S. L. L., Wang, R., Zuo, X., Zhang, C. L. & Lu, X. M. (2009). Polyhedron, doi: 10.1016/j.poly.2009.06.036.]); Effendy et al. (2007a[Effendy, Marchetti, F., Pettinari, C., Skelton, B. W. & White, A. H. (2007a). Inorg. Chim. Acta, 360, 1424-1432.],b[Effendy, Marchetti, F., Pettinari, C., Pettinari, R., Skelton, B. W. & White, A. H. (2007b). Inorg. Chim. Acta, 360, 1451-1465.]); Awaleh et al. (2005a[Awaleh, M. O., Badia, A. & Brisse, F. (2005a). Inorg. Chem. 44, 7833-7845.],b[Awaleh, M. O., Badia, A. & Brisse, F. (2005b). Cryst. Growth Des. 5, 1897-1906.]); Pettinari et al. (2007[Pettinari, C., Ngoune, J., Skelton, B. W. & White, A. H. (2007). Inorg. Chem. Commun. 10, 329-331.]). For general background, see: Howells & Mccown (1977[Howells, R. D. & Mccown, J. D. (1977). Chem. Rev. 77, 19-92.]); Bowmaker et al. (2005[Bowmaker, G. A., Effendy, Marfuah, S., Skelton, B. W. & White, A. H. (2005). Inorg. Chim. Acta, 358, 4371-4388.]); Lawrance (1986[Lawrance, G. A. (1986). Chem. Rev. 86, 17-33.]).

[Scheme 1]

Experimental

Crystal data
  • [Ag(C12H8N2)(C18H15P)]CF3SO3

  • Mr = 699.42

  • Triclinic, [P \overline 1]

  • a = 10.9832 (2) Å

  • b = 11.7533 (2) Å

  • c = 12.2642 (3) Å

  • [alpha] = 77.711 (1)°

  • [beta] = 76.183 (1)°

  • [gamma] = 73.440 (1)°

  • V = 1455.66 (5) Å3

  • Z = 2

  • Mo K[alpha] radiation

  • [mu] = 0.87 mm-1

  • T = 293 K

  • 0.4 × 0.3 × 0.2 mm

Data collection
  • Bruker SMART CCD area-detector diffractometer

  • Absorption correction: multi-scan (SADABS; Bruker, 2007[Bruker (2007). SMART, SAINT-Plus and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]) Tmin = 0.735, Tmax = 0.832

  • 18629 measured reflections

  • 9515 independent reflections

  • 6777 reflections with I > 2[sigma](I)

  • Rint = 0.021

Refinement
  • R[F2 > 2[sigma](F2)] = 0.042

  • wR(F2) = 0.133

  • S = 1.00

  • 9515 reflections

  • 379 parameters

  • H-atom parameters constrained

  • [Delta][rho]max = 0.59 e Å-3

  • [Delta][rho]min = -0.66 e Å-3

Table 1
Selected geometric parameters (Å, °)

Ag1-N2 2.2798 (18)
Ag1-N1 2.292 (2)
Ag1-P1 2.3469 (5)
N2-Ag1-N1 73.53 (8)
N2-Ag1-P1 147.77 (6)
N1-Ag1-P1 138.03 (6)

Table 2
Hydrogen-bond geometry (Å, °)

D-H...A D-H H...A D...A D-H...A
C20-H16...O2 0.93 2.36 3.285 (6) 173

Data collection: SMART (Bruker, 2007[Bruker (2007). SMART, SAINT-Plus and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT-Plus (Bruker, 2007[Bruker (2007). SMART, SAINT-Plus and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT-Plus; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); software used to prepare material for publication: SHELXTL.


Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: WM2241 ).


Acknowledgements

This work was supported by the National Science Foundation of China (grant No. 20871085), the Committee of Education of Beijing Foundation of China (grant No. KM200610028006), the Project sponsored by SRF for ROCS and SEM, the subsidy of Beijing Personnel Bureau, the National Keystone Basic Research Program (973 Program under grant Nos. 2007CB310408, No. 2006CB302901), the State Key Laboratory of Functional Materials for Informatics and the Shanghai Institute of Microsystems and Information Technology, Chinese Academy of Sciences.

References

Awaleh, M. O., Badia, A. & Brisse, F. (2005a). Inorg. Chem. 44, 7833-7845.  [ISI] [CSD] [CrossRef] [PubMed] [ChemPort]
Awaleh, M. O., Badia, A. & Brisse, F. (2005b). Cryst. Growth Des. 5, 1897-1906.  [CSD] [CrossRef] [ChemPort]
Bowmaker, G. A., Effendy, Marfuah, S., Skelton, B. W. & White, A. H. (2005). Inorg. Chim. Acta, 358, 4371-4388.  [ISI] [CSD] [CrossRef] [ChemPort]
Bruker (2007). SMART, SAINT-Plus and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
Di Nicola, C., Effendy, Marchetti, F., Pettinari, C., Skelton, B. W. & White, A. H. (2007). Inorg. Chim. Acta, 360, 1433-1450.  [ISI] [CSD] [CrossRef] [ChemPort]
Effendy, Marchetti, F., Pettinari, C., Pettinari, R., Skelton, B. W. & White, A. H. (2007b). Inorg. Chim. Acta, 360, 1451-1465.  [ISI] [CSD] [CrossRef] [ChemPort]
Effendy, Marchetti, F., Pettinari, C., Skelton, B. W. & White, A. H. (2007a). Inorg. Chim. Acta, 360, 1424-1432.  [ISI] [CSD] [CrossRef] [ChemPort]
Howells, R. D. & Mccown, J. D. (1977). Chem. Rev. 77, 19-92.  [CrossRef] [ISI]
Jin, Q. H., Hu, K. Y. S. L. L., Wang, R., Zuo, X., Zhang, C. L. & Lu, X. M. (2009). Polyhedron, doi: 10.1016/j.poly.2009.06.036.
Jin, Q. H., Xin, X. L., Zhu, F. J. & Li, Y. (1999). Z. Kristallogr. New Cryst. Struct. 214, 503-504.  [ChemPort]
Lawrance, G. A. (1986). Chem. Rev. 86, 17-33.  [CrossRef] [ChemPort] [ISI]
Pettinari, C., Ngoune, J., Skelton, B. W. & White, A. H. (2007). Inorg. Chem. Commun. 10, 329-331.  [ISI] [CSD] [CrossRef] [ChemPort]
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [details]


Acta Cryst (2009). E65, m1096-m1097   [ doi:10.1107/S1600536809032097 ]

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