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Acta Cryst. (2009). E65, o2363-o2364  [ doi:10.1107/S1600536809034837 ]

2,2,4-Trimethyl-5-(4-tolylsulfonyl)-2,3,4,5-tetrahydro-1H-1,5-benzodiazepine

K. Ravichandran, K. Sathiyaraj, S. S. Ilango, S. Ponnuswamy and M. N. Ponnuswamy

Abstract: In the title compound, C19H24N2O2S, the benzodiazepine ring adopts a distorted boat conformation. The S atom shows a distorted tetrahedral geometry, with the O-S-O [119.16 (14)°] and N-S-C [107.48 (10)°] angles deviating significantly from ideal values. The crystal packing is controlled by C-H...O, N-H...O and C-H...[pi] interactions.

Online 5 September 2009


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