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Acta Cryst. (2009). E65, m1198-m1199  [ doi:10.1107/S1600536809035958 ]

catena-Poly[[[diaquacopper(II)]-bis[[mu]2-1,3-bis(1,2,4-triazol-1-yl)propane]] dinitrate monohydrate]

W. Feng, X.-J. Zhao and E.-C. Yang

Abstract: The title CuII coordination polymer, {[Cu(C7H10N6)2(H2O)2](NO3)2·H2O}n, was obtained by the reaction of equimolar Cu(NO3)2·4H2O and 1,3-bis(1,2,4-triazol-1-yl)propane (btp) in a water-methanol solvent. The CuII atom is located on a centre of inversion and has an elongated octahedral coordination geometry formed by four N atoms from four symmetry-related btp ligands and two coordinated water molecules. Adjacent CuII atoms are connected by btp ligands, generating a double-stranded chain. The nitrate anion is disordered over two positions in a 0.828 (7):0.172 (2) ratio.

Online 12 September 2009


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