[HTML version][PDF version][CIF][3d view][Structure Factors][Supplementary Material][CIF check Report][Issue contents]  [Open access]

[Contents scheme]

Acta Cryst. (2009). E65, o2381  [ doi:10.1107/S1600536809035557 ]

A chiral photochromic Schiff base: (R)-4-methoxy-2-[(1-phenylethyl)iminomethyl]phenol

Y. Miura, Y. Aritake and T. Akitsu

Abstract: The title chiral photochromic Schiff base compound, C16H17NO2, was synthesized from (R)-1-phenylethylamine and 5-methoxysalicylaldehyde. The molecule of the title compound exists in the phenol-imine tautomeric form. The dihedral angle between the two aromatic rings is 62.61 (11)°. An intramolecular O-H...N hydrogen bond with an O...N distance of 2.589 (2) Å is observed. The crystal packing is stabilized by C-H...[pi] interactions involving the aromatic ring.

Online 9 September 2009


Copyright © International Union of Crystallography
IUCr Webmaster