Acta Cryst. (2009). E65, m1210  [ doi:10.1107/S1600536809036459 ]

1-Bromo-1'-(diphenylthiophosphoryl)ferrocene

P. Stepnicka, J. Schulz and I. Císarová

Abstract: The title compound, [Fe(C₅H₄Br)(C₁₇H₁₄PS)], crystallizes with two practically undistiguishable molecules in the asymmetric unit, which are related by a non-space-group inversion. The ferrocene-1,1'-diyl units exhibit a regular geometry with negligible tilting and balanced Fe-ring centroid distances, and with the attached substituents assuming conformations close to ideal synclinal eclipsed.

Online 12 September 2009

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