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Acta Cryst. (2009). E65, m1251  [ doi:10.1107/S1600536809038070 ]

Dibromido{2-hydroxy-N'-[phenyl(2-pyridyl)methylene]benzohydrazide}copper(II)

L.-Q. Kong, X.-P. Ju and D.-C. Li

Abstract: In the title complex, [CuBr2(C19H15N3O2)], the metal ion is coordinated by the N,N',O-tridentate 2-hydroxy-N'-[phenyl(2-pyridyl)methylene]benzohydrazide ligand and two bromide ions, resulting in a distorted CuN2OBr2 square-based pyramidal coordination geometry with one bromide ion in the apical site. An intramolecular N-H...O hydrogen bond occurs in the ligand. In the crystal, molecules are connected by intermolecular C-H...O, C-H...Br and O-H...Br interactions.

Online 26 September 2009


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