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Acta Cryst. (2009). E65, m1237  [ doi:10.1107/S1600536809037520 ]

catena-Poly[[pyridinecopper(II)]-[mu]-N-[(2-oxido-1-naphthyl)methylene]glycinato]

L.-W. Xue, X.-W. Li, G.-Q. Zhao and Q.-L. Peng

Abstract: In the title compound, [Cu(C13H9NO3)(C5H5N)], the CuII atom is coordinated in a distorted square-pyramidal geometry, with two N and two O atoms in the basal positions and one O atom in the apical position. The apical Cu-O bond [2.3520 (16) Å] is much longer than the basal Cu-O and Cu-N bonds [1.9139 (14)-2.0136 (17) Å]. The carboxylate group bridges CuII atoms, forming a zigzag chain along the a axis.

Online 26 September 2009


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