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Acta Cryst. (2009). E65, o2317  [ doi:10.1107/S1600536809033455 ]

1,4-Bis{(+)-(S)-[1-(1-naphthyl)ethyl]iminomethyl}benzene

A. Espinosa Leija, S. Bernès, G. Hernández, P. Sharma, U. Peña and R. Gutiérrez

Abstract: The title compound, C32H28N2, is a chiral bis-imine in which both imine groups display the common E configuration. The naphthyl groups present different orientations with respect to the central core, as reflected in the dihedral angles of 21.4 (2) and 78.83 (14)° between the benzene and naphthyl mean planes, thus the highest possible C2 local molecular symmetry is not attained. This C1 molecular conformation allows multiple C-H...[pi] intermolecular contacts involving all aromatic rings, while no [pi]-[pi] interactions are available for the stabilization of the crystal structure. The resulting packing structure is based on molecules stacked along [100].

Online 5 September 2009


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