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Acta Cryst. (2009). E65, m1176  [ doi:10.1107/S1600536809035193 ]

(2-Amino-4,6-dimethylpyrimidine-[kappa]N1)(2-amino-4-methylpyrimidine-[kappa]N1)silver(I) perchlorate

H. Yang

Abstract: Colourless crystals of the title mixed ligand complex, [Ag(C5H7N3)(C6H9N3)]ClO4, were obtained from a solution of 2-amino-4-methylpyrimidine, 2-amino-4,6-dimethylpyrimidine and silver perchlorate in water and methanol. The crystal structure is stabilized by intermolecular N-H...O and N-H...N hydrogen bonds and [pi]-[pi] stacking interactions of the aromatic rings of the two ligands [interplanar distance = 3.652 (10) Å]. The AgI atom shows a linear coordination [N-Ag-N = 174.6 (1)°].

Online 5 September 2009


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