Acta Cryst. (2009). E65, o2307  [ doi:10.1107/S1600536809034059 ]

[(Di-o-tolylphosphino)methyl]diphenylphosphine sulfide

P. P. Pitroda, A. H. Badgett, G. A. Dickey, D. L. Gray and Q. D. Shelby

Abstract: In the title compound, C₂₇H₂₆P₂S, the P-C-P angle is 114.33 (13)°. The bond distances are longer and the bond angles are smaller at the P atom bonded to the o-tolyl groups owing to the presence of a lone pair of electrons. One phenyl ring is disordered over three sites [occupancies 0.317 (8), 0.250 (8), and 0.433 (6)] and the other phenyl ring is disordered over two sites [occupancies 0.871 (6) and 0.129 (6)].

Online 5 September 2009

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