Acta Cryst. (2009). E65, m1221-m1222  [ doi:10.1107/S1600536809033388 ]

catena-Poly[[[bis(1,10-phenanthroline-²N,N')manganese(II)]--2,2'-dithiodibenzoato-²O,O] methanol hemisolvate monohydrate]

L.-M. Zhou, Q. Zhang and M. Hu

Abstract: The title complex, {[Mn(C₁₄H₈O₄S₂)(C₁₂H₈N₂)₂]·0.5CH₃OH·H₂O}_n, has a one-dimensional chain structure in which the Mn^II atom is six-coordinated by four N atoms from two 1,10-phenanthroline (phen) ligands and two O atoms from two 2,2'-dithiodibenzoate (L) ligands. The L ligands adopt a bis(monodentate) (syn-anti) coordination mode and bridge adjacent Mn^II centres, generating a chain running along [201]. Adjacent chains are linked into a two-dimensional network, parallel to (10), via interchain C-H and - stacking [centroid-centroid distance = 3.477 (1) Å] interactions. The structure also contains numerous hydrogen-bonding interactions, which further link the two-dimensional entities into a three-dimensional supramolecular network.

Online 16 September 2009

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