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Acta Cryst. (2009). E65, m1178  [ doi:10.1107/S1600536809035144 ]

Bis([mu]-cyclohexane-1,3-dicarboxylato)-[kappa]3O1:O4,O4';[kappa]3O1,O1':O4-bis[aqua(1,10-phenanthroline-[kappa]2N,N')zinc(II)]

M. R. Rizal and S. W. Ng

Abstract: The cyclohexane-1,3-dicarboxylate dianion in the dinuclear centrosymmetric title compound, [Zn2(C8H10O4)2(C12H8N2)2(H2O)2], has a chair conformation with both carboxylate groups in equatorial positions. One carboxylate group chelates a ZnII atom, whereas the other binds through one O atom only to confer a six-coordinate status to the N-heterocycle-chelated water-coordinated ZnII atom. Adjacent dinuclear molecules are linked by O-H...O hydrogen bonds into a linear chain.

Online 9 September 2009


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