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Acta Cryst. (2009). E65, m1432-m1433 [ doi:10.1107/S1600536809043475 ]
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-6-hydroxynaphthalene-1-carboxylato)bis[(6-hydroxynaphthalene-1-carboxylato)(1,10-phenanthroline)cadmium(II)] tetrahydrateAbstract: The title complex, [Cd2(C11H7O3)4(C12H8N2)2]·4H2O, has a centrosymmetric binuclear structure in which two CdII atoms are both six-coordinated and bridged by 6-hydroxynaphthalene-1-carboxylate ligands, with a Cd
Cd separation of 3.671 (1) Å. The remaining coordination sites are occupied by two N atoms of a 1,10-phenanthroline ligand and two O atoms of a 6-hydroxynaphthalene-1-carboxylate ligand. The crystal packing is stabilized by O-HO hydrogen-bonding interactions.
Online 28 October 2009
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