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Acta Cryst. (2009). E65, m1418  [ doi:10.1107/S1600536809042986 ]

([eta]6-p-Cymene)bis(trichloridostannyl)(triethoxyphosphine-[kappa]P)ruthenium(II)

S. S. Shapovalov and B. Therrien

Abstract: In the title complex, [RuSn2(C10H14)Cl6(C6H15O3P)], the Ru-Sn bond lengths [2.5619 (3) and 2.5669 (3) Å] are about 0.3 Å shorter than the sum of the covalent Ru and Sn radii (1.46 + 1.39 = 2.85 Å), in line with other structurally characterized arene ruthenium trichloridostannyl derivatives. The Ru(II) atom is surrounded by a para-cymene, a triethylphosphite and two trichloridostannyl ligands in a typical piano-stool coordination.

Online 23 October 2009


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