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Acta Cryst. (2009). E65, m1412  [ doi:10.1107/S1600536809041440 ]

Poly[[bis([mu]2-6-methylpyrazin-2-carboxylato-[kappa]3N1,O:N4)copper(II)] dihydrate]

C. Fan, X.-T. Wei and L. Li

Abstract: In the title compound, {[Cu(C6H5N2O2)2]·2H2O}n, the CuII ion (site symmetry \\overline{1}) is coordinated by two N,O-bidentate ligands and two N-monodentate ligands in a distorted CuO2N4 octahedral geometry. Each anion acts as a bridge between two cations, thus forming a two-dimensional polymeric network parallel to the ab plane. The packing is consolidated by O-H...O hydrogen bonds. One of the O atoms of the ligand and both water molecules are disordered.

Online 23 October 2009


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