metal-organic compounds\(\def\hfill{\hskip 5em}\def\hfil{\hskip 3em}\def\eqno#1{\hfil {#1}}\)

Journal logoCRYSTALLOGRAPHIC
COMMUNICATIONS
ISSN: 2056-9890

Poly[[bis­­(μ2-6-methyl­pyrazin-2-carboxyl­ato-κ3N1,O:N4)copper(II)] dihydrate]

aDepartment of Chemistry and Chemical Engineering, Binzhou University, Shandong 256603, People's Republic of China, and bCollege of Chemistry and Chemical Engineering, Liaocheng University, Shandong 252059, People's Republic of China
*Correspondence e-mail: xintingwei@cn.yahoo.com

(Received 29 September 2009; accepted 11 October 2009; online 23 October 2009)

In the title compound, {[Cu(C6H5N2O2)2]·2H2O}n, the CuII ion (site symmetry [\overline{1}]) is coordinated by two N,O-bidentate ligands and two N-monodentate ligands in a distorted CuO2N4 octa­hedral geometry. Each anion acts as a bridge between two cations, thus forming a two-dimensional polymeric network parallel to the ab plane. The packing is consolidated by O—H⋯O hydrogen bonds. One of the O atoms of the ligand and both water mol­ecules are disordered.

Related literature

For a related structure, see: Yigit et al. (2006[Yigit, M. V., Wang, Y., Moulton, B. & MacDonald, J. C. (2006). Cryst. Growth Des. 6, 829-832.]). For background to coordination networks, see: Kesanli & Lin (2003[Kesanli, B. & Lin, W. B. (2003). Coord. Chem. Rev. 246, 305-326.]); Barnett & Champness (2003[Barnett, S. A. & Champness, N. R. (2003). Coord. Chem. Rev. 246, 145-168.]).

[Scheme 1]

Experimental

Crystal data
  • [Cu(C6H5N2O2)2]·2H2O

  • Mr = 373.81

  • Monoclinic, P 21 /c

  • a = 8.371 (1) Å

  • b = 9.7901 (11) Å

  • c = 10.3849 (13) Å

  • β = 112.277 (1)°

  • V = 787.55 (16) Å3

  • Z = 2

  • Mo Kα radiation

  • μ = 1.42 mm−1

  • T = 298 K

  • 0.34 × 0.32 × 0.30 mm

Data collection
  • Bruker SMART CCD diffractometer

  • Absorption correction: multi-scan (SADABS; Bruker, 2003[Bruker (2003). SMART, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]) Tmin = 0.644, Tmax = 0.675

  • 3821 measured reflections

  • 1388 independent reflections

  • 1094 reflections with I > 2σ(I)

  • Rint = 0.027

Refinement
  • R[F2 > 2σ(F2)] = 0.049

  • wR(F2) = 0.160

  • S = 1.06

  • 1388 reflections

  • 126 parameters

  • H-atom parameters constrained

  • Δρmax = 1.23 e Å−3

  • Δρmin = −0.47 e Å−3

Table 1
Selected bond lengths (Å)

Cu1—O1 1.949 (3)
Cu1—N2i 2.064 (4)
Cu1—N1 2.354 (4)
Symmetry code: (i) [-x+1, y+{\script{1\over 2}}, -z+{\script{1\over 2}}].

Table 2
Hydrogen-bond geometry (Å, °)

D—H⋯A D—H H⋯A DA D—H⋯A
O3—H3C⋯O2ii 0.85 1.78 2.624 (3) 175
O3—H3C⋯O2′ii 0.85 2.36 3.181 (3) 163
O3—H3D⋯O2′i 0.85 2.23 3.074 (2) 175
O4—H4D⋯O3iii 0.85 1.97 2.73 (3) 147
O4—H4E⋯O3iv 0.85 2.01 2.77 (2) 150
Symmetry codes: (i) [-x+1, y+{\script{1\over 2}}, -z+{\script{1\over 2}}]; (ii) x+1, y, z; (iii) x, y, z+1; (iv) -x+1, -y+1, -z+1.

Data collection: SMART (Bruker, 2003[Bruker (2003). SMART, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 2003[Bruker (2003). SMART, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); software used to prepare material for publication: SHELXTL.

Supporting information


Comment top

In recent years,the construction of metal-organic coordination polymers (MOCPs) by metal-directed self- assembly is of great interest not only for their potential applications as functional materials in ion exchange, catalysis, hydrogen storage, and magnetic devices, but also for their aesthetic structural and host–guest chemistry associated with large central cavities. (Kesanli et al., 2003; Barnett et al., 2003). As an extension of this work,the 6-methyl-2- pyrazinecarboxylic acid was chosen due to its chelating coordinated effect leading to a linear metal center.

As shown in Fig.1. X-ray structural analyses of complex (1) reveal the core structure of (1) is the symmetric dinuclear unit of [Cu(L)2(H2O)2] (L = anion of 6-methyl-2- pyrazinecarboxylic acid). Each CuII atom is coordinated to two ligands as well as to the two N atoms of the other two ligands, forming a octahedral coordination conformation.

The ligand forms a coordination polymer with tridentate and monodentate binding of CuII ions at opposite ends of the ligand bridge neighboring units and yield a two-dimensional arrangement running in the ab plane (Fig. 2). Yigit et al. (2006) recently reported a coordination polymer featuring a similar head-to-tail arrangement of pyrazine-2,3,5,6-tetracarboxylic acid. There is intermolecular H-bonds (O3—H3···O4) showed as strong H bond, which link the molecular and water to form host–guest model.

Related literature top

For a related structure, see: Yigit et al. (2006). For background to coordination networks, see: Kesanli & Lin (2003); Barnett & Champness (2003).

Experimental top

4.00 g Potassium permanganate was to be dissolved in 30 ml pure water in a beaker and 1.0 ml 98% H2SO4 was added to the solution. After stiring 10 min, and then added 2,6-dimethylpyrazine to the mixture.The recation was keeping at room temperature for 24 h. The resulting solution was filtered, and the filtrate was left in a beaker, then 2.00 g copper(II) sulfate pentahydrate was added to the filtrate. After stirrng for 20 min s, the copper(II) sulfate pentahydrate was solved completely. The blue solution was kept at the room temperature for two weeks and blue blocks of (I) were obtained. Yield: 86percent, m.p. 551 K. Anal. Calc. for C12H14CuN4O6: C: 38.5567; H:3.7750; N:14.9881; Found:C: 37.67; H: 3.86; N: 14.32%. Selected IR (KBr, cm-1) 3439(w), 2889 (w), 1638(s), 1596 (s), 1536(w), 1409(s), 1364(m), 1275(m), 1149(s), 1151(s), 1034(s), 941(s), 820(m), 800(s), 712(w), 531(m), 471(w).

Refinement top

All H atoms were placed geometrically and treated as riding on their parent atoms with C—H 0.93(pyrazine), C—H 0.97 (methylene) Å [Uiso(H) = 1.2Ueq(C)] and O—H 0.82 Å (hydroxyl) [Uiso(H) = 1.5Ueq(O)].

Structure description top

In recent years,the construction of metal-organic coordination polymers (MOCPs) by metal-directed self- assembly is of great interest not only for their potential applications as functional materials in ion exchange, catalysis, hydrogen storage, and magnetic devices, but also for their aesthetic structural and host–guest chemistry associated with large central cavities. (Kesanli et al., 2003; Barnett et al., 2003). As an extension of this work,the 6-methyl-2- pyrazinecarboxylic acid was chosen due to its chelating coordinated effect leading to a linear metal center.

As shown in Fig.1. X-ray structural analyses of complex (1) reveal the core structure of (1) is the symmetric dinuclear unit of [Cu(L)2(H2O)2] (L = anion of 6-methyl-2- pyrazinecarboxylic acid). Each CuII atom is coordinated to two ligands as well as to the two N atoms of the other two ligands, forming a octahedral coordination conformation.

The ligand forms a coordination polymer with tridentate and monodentate binding of CuII ions at opposite ends of the ligand bridge neighboring units and yield a two-dimensional arrangement running in the ab plane (Fig. 2). Yigit et al. (2006) recently reported a coordination polymer featuring a similar head-to-tail arrangement of pyrazine-2,3,5,6-tetracarboxylic acid. There is intermolecular H-bonds (O3—H3···O4) showed as strong H bond, which link the molecular and water to form host–guest model.

For a related structure, see: Yigit et al. (2006). For background to coordination networks, see: Kesanli & Lin (2003); Barnett & Champness (2003).

Computing details top

Data collection: SMART (Bruker, 2003); cell refinement: SAINT (Bruker, 2003); data reduction: SAINT (Bruker, 2003); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL (Sheldrick, 2008).

Figures top
[Figure 1] Fig. 1. The molecular structure of (I) showing 30% probability displacement ellipsoids.
[Figure 2] Fig. 2. The crystal packing of (I), viewed approximately along the c axis.
Poly[[bis(µ2-6-methylpyrazin-2-carboxylato- κ3N1,O:N4)copper(II)] dihydrate] top
Crystal data top
[Cu(C6H5N2O2)2]·2H2OF(000) = 382
Mr = 373.81Dx = 1.576 Mg m3
Monoclinic, P21/cMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybcCell parameters from 1598 reflections
a = 8.371 (1) Åθ = 2.6–26.2°
b = 9.7901 (11) ŵ = 1.42 mm1
c = 10.3849 (13) ÅT = 298 K
β = 112.277 (1)°Block, blue
V = 787.55 (16) Å30.34 × 0.32 × 0.30 mm
Z = 2
Data collection top
Bruker SMART CCD
diffractometer
1388 independent reflections
Radiation source: fine-focus sealed tube1094 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.027
ω scansθmax = 25.0°, θmin = 2.6°
Absorption correction: multi-scan
(SADABS; Bruker, 2003)
h = 99
Tmin = 0.644, Tmax = 0.675k = 1111
3821 measured reflectionsl = 129
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.049Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.160H-atom parameters constrained
S = 1.06 w = 1/[σ2(Fo2) + (0.0987P)2 + 1.8186P]
where P = (Fo2 + 2Fc2)/3
1388 reflections(Δ/σ)max = 0.001
126 parametersΔρmax = 1.23 e Å3
0 restraintsΔρmin = 0.47 e Å3
Crystal data top
[Cu(C6H5N2O2)2]·2H2OV = 787.55 (16) Å3
Mr = 373.81Z = 2
Monoclinic, P21/cMo Kα radiation
a = 8.371 (1) ŵ = 1.42 mm1
b = 9.7901 (11) ÅT = 298 K
c = 10.3849 (13) Å0.34 × 0.32 × 0.30 mm
β = 112.277 (1)°
Data collection top
Bruker SMART CCD
diffractometer
1388 independent reflections
Absorption correction: multi-scan
(SADABS; Bruker, 2003)
1094 reflections with I > 2σ(I)
Tmin = 0.644, Tmax = 0.675Rint = 0.027
3821 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.0490 restraints
wR(F2) = 0.160H-atom parameters constrained
S = 1.06Δρmax = 1.23 e Å3
1388 reflectionsΔρmin = 0.47 e Å3
126 parameters
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Cu10.50000.50000.50000.0210 (3)
N10.5565 (5)0.3429 (4)0.3509 (4)0.0273 (9)
N20.5246 (5)0.1511 (4)0.1450 (4)0.0270 (9)
O10.2704 (4)0.4333 (3)0.3861 (3)0.0259 (7)
O20.1014 (18)0.343 (6)0.184 (5)0.049 (10)0.46 (9)
O2'0.1110 (16)0.279 (5)0.235 (4)0.049 (9)0.54 (9)
O30.8445 (18)0.5171 (12)0.0914 (16)0.097 (4)0.50
H3C0.93070.46390.12480.116*0.50
H3D0.86310.58770.14260.116*0.50
O40.499 (3)0.4908 (16)0.9398 (18)0.126 (6)0.50
H4D0.59040.50251.01210.152*0.50
H4E0.41220.49290.96280.152*0.50
C10.2469 (6)0.3484 (6)0.2899 (6)0.0411 (14)
C20.4033 (6)0.2942 (5)0.2678 (5)0.0302 (11)
C30.3863 (6)0.1987 (6)0.1653 (5)0.0337 (12)
H30.27710.16720.10960.040*
C40.6768 (6)0.1996 (5)0.2266 (5)0.0319 (11)
H4A0.77500.16820.21460.038*
C50.6955 (6)0.2969 (5)0.3308 (5)0.0301 (11)
C60.8676 (7)0.3506 (7)0.4211 (6)0.0496 (16)
H6A0.85320.42830.47210.074*
H6B0.93000.37750.36440.074*
H6C0.93090.28090.48500.074*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Cu10.0214 (5)0.0226 (5)0.0193 (5)0.0019 (3)0.0079 (3)0.0006 (3)
N10.023 (2)0.033 (2)0.026 (2)0.0023 (17)0.0093 (16)0.0047 (17)
N20.025 (2)0.031 (2)0.027 (2)0.0020 (18)0.0120 (16)0.0056 (17)
O10.0234 (16)0.0301 (18)0.0267 (17)0.0018 (14)0.0124 (13)0.0062 (15)
O20.025 (5)0.065 (19)0.054 (13)0.004 (6)0.012 (5)0.030 (15)
O2'0.025 (4)0.065 (17)0.054 (11)0.004 (5)0.012 (5)0.030 (12)
O30.074 (8)0.092 (10)0.115 (11)0.018 (6)0.026 (8)0.013 (7)
O40.120 (14)0.133 (15)0.129 (17)0.002 (9)0.050 (14)0.000 (11)
C10.019 (3)0.058 (4)0.045 (3)0.004 (2)0.010 (2)0.019 (3)
C20.025 (3)0.033 (3)0.032 (3)0.004 (2)0.010 (2)0.010 (2)
C30.025 (3)0.041 (3)0.035 (3)0.004 (2)0.011 (2)0.012 (2)
C40.023 (3)0.040 (3)0.034 (3)0.002 (2)0.012 (2)0.007 (2)
C50.026 (3)0.032 (3)0.033 (3)0.002 (2)0.012 (2)0.006 (2)
C60.024 (3)0.068 (4)0.054 (4)0.001 (3)0.011 (3)0.027 (3)
Geometric parameters (Å, º) top
Cu1—O1i1.949 (3)O3—H3C0.8500
Cu1—O11.949 (3)O3—H3D0.8500
Cu1—N2ii2.064 (4)O4—O4v1.26 (3)
Cu1—N2iii2.064 (4)O4—H4D0.8500
Cu1—N1i2.354 (4)O4—H4E0.8500
Cu1—N12.354 (4)C1—C21.509 (7)
N1—C21.333 (6)C2—C31.383 (7)
N1—C51.336 (6)C3—H30.9300
N2—C41.322 (6)C4—C51.405 (7)
N2—C31.337 (6)C4—H4A0.9300
N2—Cu1iv2.065 (4)C5—C61.486 (7)
O1—C11.256 (6)C6—H6A0.9600
O2—C11.30 (3)C6—H6B0.9600
O2'—C11.26 (2)C6—H6C0.9600
O1i—Cu1—O1180.0H4D—O4—H4E109.0
O1i—Cu1—N2ii89.70 (14)O1—C1—O2'124.0 (8)
O1—Cu1—N2ii90.30 (14)O1—C1—O2121.0 (11)
O1i—Cu1—N2iii90.30 (14)O2'—C1—O236.7 (6)
O1—Cu1—N2iii89.70 (14)O1—C1—C2118.1 (4)
N2ii—Cu1—N2iii180.0O2'—C1—C2115.3 (8)
O1i—Cu1—N1i77.27 (13)O2—C1—C2116.5 (8)
O1—Cu1—N1i102.73 (13)N1—C2—C3122.2 (5)
N2ii—Cu1—N1i88.74 (15)N1—C2—C1116.9 (4)
N2iii—Cu1—N1i91.26 (15)C3—C2—C1120.9 (4)
O1i—Cu1—N1102.73 (13)N2—C3—C2121.0 (4)
O1—Cu1—N177.27 (13)N2—C3—H3119.5
N2ii—Cu1—N191.26 (15)C2—C3—H3119.5
N2iii—Cu1—N188.74 (15)N2—C4—C5122.4 (4)
N1i—Cu1—N1180.0N2—C4—H4A118.8
C2—N1—C5117.4 (4)C5—C4—H4A118.8
C2—N1—Cu1106.0 (3)N1—C5—C4120.0 (4)
C5—N1—Cu1136.6 (3)N1—C5—C6118.4 (4)
C4—N2—C3117.1 (4)C4—C5—C6121.6 (4)
C4—N2—Cu1iv122.0 (3)C5—C6—H6A109.5
C3—N2—Cu1iv120.8 (3)C5—C6—H6B109.5
C1—O1—Cu1121.7 (3)H6A—C6—H6B109.5
H3C—O3—H3D108.5C5—C6—H6C109.5
O4v—O4—H4D55.8H6A—C6—H6C109.5
O4v—O4—H4E53.3H6B—C6—H6C109.5
O1i—Cu1—N1—C2179.1 (3)C5—N1—C2—C1179.1 (5)
O1—Cu1—N1—C20.9 (3)Cu1—N1—C2—C10.0 (5)
N2ii—Cu1—N1—C290.9 (3)O1—C1—C2—N11.4 (8)
N2iii—Cu1—N1—C289.1 (3)O2'—C1—C2—N1164 (3)
N1i—Cu1—N1—C2168 (100)O2—C1—C2—N1155 (4)
O1i—Cu1—N1—C50.4 (5)O1—C1—C2—C3178.9 (5)
O1—Cu1—N1—C5179.6 (5)O2'—C1—C2—C317 (3)
N2ii—Cu1—N1—C590.4 (5)O2—C1—C2—C324 (4)
N2iii—Cu1—N1—C589.6 (5)C4—N2—C3—C20.2 (8)
N1i—Cu1—N1—C513 (100)Cu1iv—N2—C3—C2176.2 (4)
O1i—Cu1—O1—C15 (100)N1—C2—C3—N20.1 (8)
N2ii—Cu1—O1—C193.0 (4)C1—C2—C3—N2179.6 (5)
N2iii—Cu1—O1—C187.0 (4)C3—N2—C4—C50.0 (8)
N1i—Cu1—O1—C1178.2 (4)Cu1iv—N2—C4—C5176.3 (4)
N1—Cu1—O1—C11.8 (4)C2—N1—C5—C40.8 (7)
Cu1—O1—C1—O2'163 (3)Cu1—N1—C5—C4179.5 (4)
Cu1—O1—C1—O2153 (4)C2—N1—C5—C6179.4 (5)
Cu1—O1—C1—C22.4 (7)Cu1—N1—C5—C60.7 (8)
C5—N1—C2—C30.6 (7)N2—C4—C5—N10.5 (8)
Cu1—N1—C2—C3179.7 (4)N2—C4—C5—C6179.7 (5)
Symmetry codes: (i) x+1, y+1, z+1; (ii) x, y+1/2, z+1/2; (iii) x+1, y+1/2, z+1/2; (iv) x+1, y1/2, z+1/2; (v) x+1, y+1, z+2.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O3—H3C···O2vi0.851.782.624 (3)175
O3—H3C···O2vi0.852.363.181 (3)163
O3—H3D···O2iii0.852.233.074 (2)175
O4—H4D···O3vii0.851.972.73 (3)147
O4—H4E···O3i0.852.012.77 (2)150
Symmetry codes: (i) x+1, y+1, z+1; (iii) x+1, y+1/2, z+1/2; (vi) x+1, y, z; (vii) x, y, z+1.

Experimental details

Crystal data
Chemical formula[Cu(C6H5N2O2)2]·2H2O
Mr373.81
Crystal system, space groupMonoclinic, P21/c
Temperature (K)298
a, b, c (Å)8.371 (1), 9.7901 (11), 10.3849 (13)
β (°) 112.277 (1)
V3)787.55 (16)
Z2
Radiation typeMo Kα
µ (mm1)1.42
Crystal size (mm)0.34 × 0.32 × 0.30
Data collection
DiffractometerBruker SMART CCD
Absorption correctionMulti-scan
(SADABS; Bruker, 2003)
Tmin, Tmax0.644, 0.675
No. of measured, independent and
observed [I > 2σ(I)] reflections
3821, 1388, 1094
Rint0.027
(sin θ/λ)max1)0.596
Refinement
R[F2 > 2σ(F2)], wR(F2), S 0.049, 0.160, 1.06
No. of reflections1388
No. of parameters126
H-atom treatmentH-atom parameters constrained
Δρmax, Δρmin (e Å3)1.23, 0.47

Computer programs: SMART (Bruker, 2003), SAINT (Bruker, 2003), SHELXS97 (Sheldrick, 2008), SHELXL97 (Sheldrick, 2008), SHELXTL (Sheldrick, 2008).

Selected bond lengths (Å) top
Cu1—O11.949 (3)Cu1—N12.354 (4)
Cu1—N2i2.064 (4)
Symmetry code: (i) x+1, y+1/2, z+1/2.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O3—H3C···O2ii0.851.782.624 (3)175
O3—H3C···O2'ii0.852.363.181 (3)163
O3—H3D···O2'i0.852.233.074 (2)175
O4—H4D···O3iii0.851.972.73 (3)147
O4—H4E···O3iv0.852.012.77 (2)150
Symmetry codes: (i) x+1, y+1/2, z+1/2; (ii) x+1, y, z; (iii) x, y, z+1; (iv) x+1, y+1, z+1.
 

References

First citationBarnett, S. A. & Champness, N. R. (2003). Coord. Chem. Rev. 246, 145–168.  Web of Science CrossRef CAS Google Scholar
First citationBruker (2003). SMART, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.  Google Scholar
First citationKesanli, B. & Lin, W. B. (2003). Coord. Chem. Rev. 246, 305–326.  Web of Science CrossRef CAS Google Scholar
First citationSheldrick, G. M. (2008). Acta Cryst. A64, 112–122.  Web of Science CrossRef CAS IUCr Journals Google Scholar
First citationYigit, M. V., Wang, Y., Moulton, B. & MacDonald, J. C. (2006). Cryst. Growth Des. 6, 829–832.  Web of Science CrossRef CAS Google Scholar

This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.

Journal logoCRYSTALLOGRAPHIC
COMMUNICATIONS
ISSN: 2056-9890
Follow Acta Cryst. E
Sign up for e-alerts
Follow Acta Cryst. on Twitter
Follow us on facebook
Sign up for RSS feeds