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Acta Cryst. (2009). E65, m1415  [ doi:10.1107/S1600536809042767 ]

[(Z)-Isopropoxy(4-nitrophenylimino)methanethiolato-[kappa]S](tricyclohexylphosphine-[kappa]P)gold(I)

S. Y. Ho and E. R. T. Tiekink

Abstract: In the title compound, [Au(C10H11N2O3S)(C18H33P)], the gold(I) atom is linearly coordinated within a SP donor set. The distortion from linearity [S-Au-P = 177.54 (3)°] can be traced to an intramolecular Au...O contact of 3.009 (3) Å. In the crystal, layers of molecules are stabilized by a combination of C-H...O and C-H...[pi] interactions.

Online 23 October 2009


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