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Acta Cryst. (2009). E65, m1468  [ doi:10.1107/S1600536809043876 ]

[(Z)-O-Ethyl N-(4-nitrophenyl)thiocarbamato-[kappa]S](triphenylphosphine-[kappa]P)gold(I) dichloromethane solvate

S. Y. Ho and E. R. T. Tiekink

Abstract: An S,P-donor set in the title solvate, [Au(C9H9N2O3S)(C18H15P)]·CH2Cl2, defines a linear geometry for the AuI atom [S-Au-P = 177.75 (7)°], with the minor distortion ascribed to the influence of an intramolecular Au...O contact [3.019 (6) Å]. In the crystal, the packing is stabilized by a network of C-H...S, C-H...N and C-H...O contacts.

Online 31 October 2009


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