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Acta Cryst. (2009). E65, m1451  [ doi:10.1107/S1600536809043554 ]

[mu]-2-Aminoterephthalato-[kappa]2O1:O4-bis[triphenyltin(IV)]

W. Li, H. Yin, L. Dong, J. Li and Q. Zhang

Abstract: The title compound, [Sn2(C6H5)6(C8H5NO4)], contains two triphenyltin groups bridged by a 2-aminoterephthalate ligand. The two SnIV centers have similar distorted tetrahedral coordination geometries. Each SnIV atom is bonded to three phenyl C atoms and one O atom from a carboxylate group. The other O atom of the carboxylate group has a weak interaction with the Sn atom. The amino group is disordered over two sites, with site-occupancy factors of 0.779 (11) and 0.221 (11). Intramolecular N-H...O hydrogen bonds are observed.

Online 28 October 2009


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