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Acta Cryst. (2009). E65, m1313  [ doi:10.1107/S1600536809039981 ]

catena-Poly[[triphenyltin(IV)]-[mu]-2-(2-picolinoylhydrazono)propanoato-[kappa]2O1:O2]

J. Cui, Y. Qiao, L. Ding and H. Yin

Abstract: In the title polymeric coordination compound, [Sn(C6H5)3(C9H8N3O3)]n, the SnIV atom is in a distorted trigonal-bipyramidal geometry, being coordinated by two O atoms from two 2-(2-picolinoylhydrazono)propanoate ligands and three phenyl groups. Adjacent Sn atoms are bridged by the 2-(2-picolinoylhydrazono)propanoate ligand through one carbonyl O atom and one carboxylate O atom, forming a chain structure propagating parallel to [100]. An intramolecular N-H...O hydrogen bond is observed.

Online 7 October 2009


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