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Acta Cryst. (2009). E65, m1486  [ doi:10.1107/S1600536809042731 ]

([eta]6-Benzophenone)([eta]5-pentamethylcyclopentadienyl)ruthenium(II) tetraphenylborate

B. T. Loughrey, K. Nadin, M. L. Williams and P. C. Healy

Abstract: The structure of the title compound, [Ru(C10H15)(C13H10O)](C24H20B), consists of discrete [Cp*Ru(II)benzophenone] cations and tetraphenylborate anions (Cp* = pentamethylcyclopentadienyl). Tethering the Cp*Ru group to one aryl ring of benzophenone results in average values of 1.42 (1) and 1.38 (1) Å for the C-C bond lengths in the Ru-tethered and untethered phenyl rings, respectively. The dihedral angle between the benzene and phenyl rings of the benzophenone group is 50.5 (1)°.

Online 31 October 2009


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