[HTML version][PDF version][CIF][3d view][Structure Factors][Supplementary Material][CIF check Report][Issue contents]  [Open access]

[Contents scheme]

Acta Cryst. (2009). E65, m1413  [ doi:10.1107/S1600536809042597 ]

Bis(2,2'-bipyridine-[kappa]2N,N')dibromidocadmium(II)

B.-S. Zhang

Abstract: In the title complex molecule, [CdBr2(C10H8N2)2], the CdII ion is six-coordinated by two cis-arranged bromide anions and four N atoms of two bidentate 2,2'-bipyridine ligands in a distorted octahedral geometry. The dihedral angle formed by the mean planes through the bipyridine ligands is 87.01 (11)°. In the crystal packing, [pi]-[pi] stacking interactions [centroid-centroid distances = 3.837 (6) and 3.867 (11) Å] link adjacent complex molecules into chains running parallel to the b axis. The chains are further connected by intermolecular C-H...Br hydrogen bonds into a three-dimensional network.

Online 23 October 2009


Copyright © International Union of Crystallography
IUCr Webmaster