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Acta Cryst. (2009). E65, m1305  [ doi:10.1107/S1600536809039257 ]

Bis{2-(5-hydroxy-2-[1-(hydroxyimino)ethyl]phenolato-[kappa]2O1,N}nickel(II) N,N-dimethylformamide disolvate

Y.-Q. Dang

Abstract: The Ni atom of the title complex, [Ni(C8H8NO3)2]·2C3H7NO, lies on a center of inversion in a square-planar N2O2 coordination environment. An intramolecular O-H...O hydrogen bond exists between the oximic hydroxy group of one ligand and the metal-coordinated O atom of the symmetry-related ligand. The dimethylformamide solvent molecules are connected to the phenolate groups of the complex via O-H...O hydrogen bonds.

Online 3 October 2009


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