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Acta Cryst. (2009). E65, m1460  [ doi:10.1107/S1600536809043360 ]

A coordination polymer of CdII with benzene-1,3-dicarboxylate and 1,4-bis[1-(2-pyridylmethyl)benzimidazol-2-yl]butane

W.-P. Zhang, W.-X. Zhao, G.-H. Cui and S.-F. Dong

Abstract: The title CdII coordination polymer, catena-poly[[{1,4-bis[1-(2-pyridylmethyl)benzimidazol-2-yl]butane}cadmium(II)]-[mu]-benzene-1,3-dicarboxylato], [Cd(C8H4O4)(C30H28N6)]n, was obtained by reaction of CdCO3, benzene-1,3-dicarboxylic acid (H2btc) and 1,4-bis[1-(2-pyridylmethyl)benzimidazol-2-yl]butane (L). The CdII cation is six-coordinated by an N2O4-donor set. L acts as a bidentate ligand and btc anions link CdII centers into a chain propagating parallel to [010].

Online 28 October 2009


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