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Acta Cryst. (2009). E65, m1292 [ doi:10.1107/S1600536809039701 ]
![[kappa]](/logos/entities/kappa_rmgif.gif)
2N,N')dibromidopalladium(II) dichloromethane solvateAbstract: In the title compound, [PdBr2(C10H8N2)]·CH2Cl2, the Pd2+ ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 2,2'-bipyridine ligand and two bromide ions. The compound displays intramolecular C-H
Br hydrogen bonds and pairs of complex molecules are assembled by intermolecular C-HBr hydrogen bonds. These pairs are connected by additional C-HBr hydrogen bonds, forming a layer structure extending parallel to (011). Intermolecular ![[pi]](/logos/entities/pi_rmgif.gif)
- interactions between the pyridine rings of the ligand are also present, the shortest centroid-centroid distance being 4.090 (9) Å.
Online 3 October 2009
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