Acta Cryst. (2009). E65, m1524-m1525  [ doi:10.1107/S1600536809046078 ]

Bis(1-ferrocenylmethylidene-4-phenylthiosemicarbazidato-²N¹,S)zinc(II) monohydrate

M. R. Vikneswaran, S. G. Teoh, C. S. Yeap and H.-K. Fun

Abstract: In the title compound, [Fe₂Zn(C₅H₅)₂(C₁₃H₁₁N₃S)₂]·H₂O, the Zn^II ion is in a distorted tetrahedral geometry being coordinated by two thiosemicarbazone ligands via N and S atoms. One of the Cp rings is disordered over two positions with occupancies of 0.55 and 0.45. The dihedral angle between the substituted Cp rings is 56.1 (5)° and the two phenyl rings are orientated at a dihedral angle of 41.7 (4)°. In the crystal structure, intermolecular O-HS, N-HO and C-HN hydrogen bonds link the molecules into chains along the b axis. The structure is further consolidated by O-H interactions.

Online 7 November 2009

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