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Acta Cryst. (2009). E65, m1545 [ doi:10.1107/S1600536809046327 ]
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5-cyclopentadienyl)bis[(dec-9-en-1-yl)diphenylphosphine]dimolybdenum(0)(Mo-Mo) tetrahydrofuran disolvateAbstract: The asymmetric unit of the title compound, [Mo2(5-C5H5)2(C22H29P)2(CO)4]·2C4H8O, contains two half-molecules of the organometallic species and two solvent molecules. Both organometallic molecules are completed by crystallographic inversion symmetry, yielding dimeric units with Mo-Mo single-bond lengths of 3.2703 (6) and 3.2548 (6) Å. Each Mo atom is also coordinated by an 5-cyclopentdienyl ligand, two carbonyl ligands, and a (dec-9-en-1-yl)diphenylphosphine ligand.
Online 11 November 2009
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