Acta Cryst. (2009). E65, o2973-o2974  [ doi:10.1107/S1600536809045267 ]

3-Benzyl-7-chloro-9-phenyl-2-tosyl-2,3,3a,4,9,9a-hexahydro-1H-pyrrolo[3,4-b]quinoline

K. Chinnakali, D. Sudha, M. Jayagobi, R. Raghunathan and H.-K. Fun

Abstract: In the title compound, C₃₁H₂₉ClN₂O₂S, the pyrrolidine ring adopts an envelope conformation with the methine C atom adjacent to the NH group as the flap atom. The tetrahydropyridine ring has a half-chair conformation. The two rings are trans-fused. The chlorobenzene ring and the adjacent phenyl ring form a dihedral angle of 77.9 (1)°. The benzyl phenyl and the tosyl phenyl rings are oriented at a dihedral angle of 88.0 (1)°. In the crystal, molecules are linked into chains along the a axis by N-HCl and C-HCl hydrogen bonds and the adjacent chains are cross-linked via C-H interactions.

Online 4 November 2009

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