Acta Cryst. (2009). E65, m1597  [ doi:10.1107/S1600536809047898 ]

[-1,1'-Bis(diphenylphosphino)ferrocene-²P:P']bis{[(Z)-O-isopropyl-N-(4-methylphenyl)thiocarbamato-S]gold(I)}

P. P. Tadbuppa and E. R. T. Tiekink

Abstract: In the title compound, [Au₂Fe(C₁₁H₁₄NOS)₂(C₁₇H₁₄P)₂], the Fe^II atom is located on a crystallographic centre of inversion. For the Au^I atom, the deviation from linearity defined by its S,P-donor set [S-Au-P = 178.17 (8) Å] is due to an intramolecular AuO contact [3.079 (4) Å]. In the crystal, supramolecular chains mediated by C-HN interactions are formed, which run parallel to [001].

Online 18 November 2009

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