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Acta Cryst. (2009). E65, m1646  [ doi:10.1107/S160053680904906X ]

[(Z)-N-(2-Chlorophenyl)-O-methylthiocarbamato-[kappa]S](triphenylphosphine-[kappa]P)gold(I)

P. P. Tadbuppa and E. R. T. Tiekink

Abstract: In the title compound, [Au(C8H7ClNOS)(C18H15P)], the AuI atom has a near-linear geometry, defined by an S,P-donor set [S-Au-P = 175.09 (5)°]. The proximity of the methoxy O atom to Au may be responsible for the deviation from linearity [Au...O = 2.959 (4) Å].

Online 21 November 2009


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