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Acta Cryst. (2009). E65, m1667-m1668  [ doi:10.1107/S1600536809049678 ]

(2,2'-Bipyridyl)bis[N,N-bis(2-hydroxyethyl)dithiocarbamato-[kappa]2S,S']cadmium(II)

J. C. Song and E. R. T. Tiekink

Abstract: The title compound, [Cd(C5H10NO2S2)2(C10H8N2)], features a trigonal-prismatic coordination geometry for the CdII ion, based on an N2S4 donor set defined by two chelating dithiocarbamate ligands and a 2,2'-bipyridyl ligand. In the crystal, extensive O-H...O hydrogen bonding results in the formation of 12-membered {...HO}6 synthons and one-dimensional supramolecular chains with further O-H...S interactions providing additional stability to the linear chain with base vector [01\\overline{1}].

Online 25 November 2009


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