Acta Cryst. (2009). E65, m1557  [ doi:10.1107/S1600536809046893 ]

[(Z)-N-Isopropyl-O-methylthiocarbamato-S](tri-p-tolylphosphine-P)gold(I)

P. P. Tadbuppa and E. R. T. Tiekink

Abstract: In the title compound, [Au(C₅H₁₀NOS)(C₂₁H₂₁P)], two independent molecules comprise the asymmetric unit, and these are connected by an aurophilic interaction [AuAu = 3.1351 (3) Å]. Each Au^I atom is linearly coordinated within a S,P-donor set with the distortion from ideal linear geometry [S-Au-P = 175.31 (5) and 176.45 (5)°] ascribed to an intramolecular AuO contact in each case [2.974 (4) and 3.027 (4) Å].

Online 11 November 2009

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