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Acta Cryst. (2009). E65, m1678-m1679  [ doi:10.1107/S1600536809049769 ]

Bis(4-aminobenzenesulfonato-[kappa]O)bis(propane-1,3-diamine-[kappa]2N,N')copper(II) dihydrate

K.-J. Zhang, X.-G. Meng and X.-L. Li

Abstract: In the title compound, [Cu(C3H10N2)2(C6H6NO3S)2]·2H2O, the CuII atom lies on an inversion center and is hexacoordinated by four N atoms from two 1,3-diaminopropane ligands and two O atoms from two 4-aminobenzenesulfonate ligands in a trans arrangement, displaying a distorted and axially elongated octahedral coordination geometry, with the O atoms at the axial positions. A three-dimensional network is formed in the crystal structure through O-H...O, N-H...O and N-H...N hydrogen bonds.

Online 25 November 2009


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