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Acta Cryst. (2009). E65, m1602-m1603  [ doi:10.1107/S1600536809048090 ]

Chlorido(dimethyl sulfoxide-[kappa]O)triphenyltin(IV)

S. Kumar, S. M. Shadab and M. Idrees

Abstract: In the title compound, [Sn(C6H5)3Cl(C2H6OS)], the SnIV atom is coordinated by three phenyl groups, a chloride ion and a dimethyl sulfoxide molecule in a distorted trigonal-bipyramidal geometry. In the crystal, adjacent molecules are linked through intermolecular C-H...Cl hydrogen bonds, weak C-H...[pi] interactions and [pi]-[pi] interactions [centroid-centroid distance = 3.934 (3) Å. An intramolecular C-H...[pi] interaction is also observed.

Online 18 November 2009


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