Acta Cryst. (2009). E65, m1653-m1654  [ doi:10.1107/S1600536809047400 ]

Chlorido(1-cyclopentylidene-4-ethylthiosemicarbazidato-²N¹,S)diphenyltin(IV)

R. Venkatraman, L. Sitole and F. R. Fronczek

Abstract: The Sn atom in the title compound, [Sn(C₆H₅)₂(C₈H₁₄N₃S)Cl], is pentacoordinated with a trigonal-bipyramidal coordination geometry. The 1-cyclopentylidene-4-ethylthiosemicarbazidate (cpetsc) ligand coordinates through the S atom and the N atom bonds to the cyclopentyl group, forming a five-membered ring with the Sn center. The chloride ligand and the coordinated N atom are in axial positions. In the crystal structure, intermolecular N-HCl hydrogen bonds form chains along [101].

Online 21 November 2009

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