Acta Cryst. (2009). E65, m1528-m1529  [ doi:10.1107/S1600536809043050 ]

Di--iodido-bis[acetyl(4-methyl-2,6,7-trioxa-1-phosphabicyclo[2.2.2]octane)(N-nitroso-N-oxidoaniline-²O,O')rhodium(III)]

J. A. Venter, W. Purcell and H. G. Visser

Abstract: The title compound, [Rh₂(C₆H₅N₂O₂)₂(C₂H₃O)₂I₂(C₅H₉O₃P)₂], contains a binuclear centrosymmetric Rh^III dimer bridged by iodide anions, with respective RhRh and II distances of 4.1437 (5) and 3.9144 (5) Å. The Rh^III atom is in a distorted octahedral RhCI₂O₂P coordination with considerably different Rh-I distances to the bridging iodide anions. There are no classical hydrogen-bonding interactions observed for this complex.

Online 7 November 2009

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