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Acta Cryst. (2009). E65, m1504  [ doi:10.1107/S1600536809045322 ]

Hexaaquamanganese(II) tetraaquabis(2-aminopyrazine-[kappa]N4)manganese(II) disulfate dihydrate

L.-H. Huo, S. Gao and S. W. Ng

Abstract: The reaction of manganese(II) sulfate and 2-aminopyrazine affords the title salt, [Mn(H2O)6][Mn(C4H5N3)2(H2O)4](SO4)2·2H2O. The metal atoms in the tetraaqua-coordinated and hexaaqua-coordinated cations lie on centers of inversion in octahedral geometries. The cations, anions and solvent water molecules are linked by O-H...O, N-H...O and O-H...N hydrogen bonds into a three-dimensional network.

Online 4 November 2009


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