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Acta Cryst. (2009). E65, m1615 [ doi:10.1107/S1600536809048648 ]
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2-bis(diphenylphosphino)methane]bis(2-ethane-1,2-dithiolato)-4-sulfido-2-sulfido-disulfidodimolybdenum(V)disilver(I) dimethylformamide trisolvateAbstract: Treatment of [Et4N]2[(edt)2Mo2S2(-S)2] (edt = ethanedithiolate) with two equivalents of Ag(CH3CN)4ClO4 in the presence of bis(diphenylphosphino)methane (dppm) ligand gives rise to the title tetranuclear cluster, [Ag2Mo2(C2H4S2)2S4(C25H22P2)2]·3C3H7NO. The complex molecule and one of the dimethylformamide (DMF) solvent molecules occupy special positions on a mirror plane. The molecular structure of the complex may be visualized as being built of [Mo2S2(-S)2(edt)2]2- dianions and [Ag2(dppm)2]2+ dications connected by two Ag--Sedt and two Ag-4-S bonds.
Online 21 November 2009
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