metal-organic compounds\(\def\hfill{\hskip 5em}\def\hfil{\hskip 3em}\def\eqno#1{\hfil {#1}}\)

Journal logoCRYSTALLOGRAPHIC
COMMUNICATIONS
ISSN: 2056-9890

catena-Poly[[di­iodidocadmium(II)]-μ-4,4′-di-4-pyridyl-2,2′-disulfanediyldi­pyrimidine]

aSchool of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, People's Republic of China, and School of Material Science and Engineering, Southeast University, Nanjing 211189, People's Republic of China
*Correspondence e-mail: zhuhaibin@seu.edu.cn

(Received 20 November 2009; accepted 27 November 2009; online 4 December 2009)

In the title compound, [CdI2(C18H12N6S2)]n, the 4,4′-di-4-pyridyl-2,2′-disulfanediyldipyrimidine (L) ligand bridges two CdII centers, forming polymeric zigzag chains extending along the b axis. The CdII ions are coordinated by two N atoms from two L ligands and two iodide anions in a distorted tetra­hedral geometry.

Related literature

For coordination polymers with 4,4′-dipyridine­disulfide, see: Horikoshi & Mochida (2006[Horikoshi, R. & Mochida, T. (2006). Coord. Chem. Rev. 250, 2595-2609.]). For coordination complexes with the title ligand L, see: Zhu et al. (2009[Zhu, H. B., Wang, H., Kong, F., Gou, S. H. & Sun, Y. M. (2009). J. Mol. Struct. 936, 99-103.]).

[Scheme 1]

Experimental

Crystal data
  • [CdI2(C18H12N6S2)]

  • Mr = 742.69

  • Triclinic, [P \overline 1]

  • a = 10.0145 (7) Å

  • b = 10.7294 (8) Å

  • c = 11.7217 (9) Å

  • α = 93.133 (1)°

  • β = 109.886 (1)°

  • γ = 97.726 (1)°

  • V = 1166.81 (15) Å3

  • Z = 2

  • Mo Kα radiation

  • μ = 3.78 mm−1

  • T = 298 K

  • 0.20 × 0.15 × 0.12 mm

Data collection
  • Bruker APEXII CCD area-detector diffractometer

  • Absorption correction: multi-scan (SADABS; Bruker, 2001[Bruker (2001). SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]) Tmin = 1.9, Tmax = 28.9

  • 5935 measured reflections

  • 4037 independent reflections

  • 3073 reflections with I > 2σ(I)

  • Rint = 0.015

Refinement
  • R[F2 > 2σ(F2)] = 0.027

  • wR(F2) = 0.057

  • S = 0.99

  • 4037 reflections

  • 262 parameters

  • H-atom parameters constrained

  • Δρmax = 0.35 e Å−3

  • Δρmin = −0.35 e Å−3

Data collection: APEX2 (Bruker, 2007[Bruker (2007). APEX2 and SAINT-Plus. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT-Plus (Bruker, 2007[Bruker (2007). APEX2 and SAINT-Plus. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT-Plus; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); software used to prepare material for publication: SHELXTL.

Supporting information


Comment top

Over past few years, organic aromatic disulfide has received considerable attention due to both its conformational flexibility and axial chirality (Horikoshi et al., 2006). In our previous study, we have reported two one-dimensional ZnII and FeII coordination polymers with the ligand L ( = 2, 2'-dithiobis(4-pyridin-4-ylpyrimidine) (Zhu et al., 2009). Herein, we report new one-dimensional CdII coordination chain generated by althernative linking of Cd center and ligand L.

The CdII ion in the title complex adopts a tetrahedral coordination geometry completed by two N atoms from two ligands L [Cd1—N1 2.287 (3) Å; Cd1—N6 2.289 (4) Å] and two I anions [I1—Cd1 2.6938 (4) Å; I2—Cd1 2.6962 (4) Å]. In L, the C—S—S—C torsion angle is 84.1 (2)°.

Related literature top

For coordination polymers with 4,4'-dipyridinedisulfide, see: Horikoshi et al. (2006). For coordination complexes with the title ligand L, see: Zhu et al. (2009).

Experimental top

Slowly added is the CH2Cl2 (5 ml) solution of ligand L (0.1 mmol) into the CdI2 (0.1 mmol) solution in methanol (10 ml). The mixture was kept on standing for three days to give single crystals suitable for X-ray diffraction analysis.

Refinement top

All H atoms were positioned geometrically and allowed to ride on their parent atoms, with C—H = 0.93 Å and Uiso(H) = 1.2Ueq(C).

Computing details top

Data collection: APEX2 (Bruker, 2007); cell refinement: SAINT-Plus (Bruker, 2007); data reduction: SAINT-Plus (Bruker, 2007); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL (Sheldrick, 2008).

Figures top
[Figure 1] Fig. 1. The coordination environment of the CdII center in the title compound with 30% probability displacement ellipsoids. Unlabelled atoms are related with the labelled ones by symmetry operation (x, y + 1, z). H atoms omitted for clarity.
catena-Poly[[diiodidocadmium(II)]-µ-4,4'-di-4-pyridyl-2,2'- disulfanediyldipyrimidine] top
Crystal data top
[CdI2(C18H12N6S2)]Z = 2
Mr = 742.69F(000) = 696
Triclinic, P1Dx = 2.114 Mg m3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71073 Å
a = 10.0145 (7) ÅCell parameters from 4037 reflections
b = 10.7294 (8) Åθ = 2.3–25.5°
c = 11.7217 (9) ŵ = 3.78 mm1
α = 93.133 (1)°T = 298 K
β = 109.886 (1)°Block, colourless
γ = 97.726 (1)°0.20 × 0.15 × 0.12 mm
V = 1166.81 (15) Å3
Data collection top
Bruker APEXII CCD area-detector
diffractometer
4037 independent reflections
Radiation source: fine-focus sealed tube3073 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.015
ϕ and ω scansθmax = 25.0°, θmin = 1.9°
Absorption correction: multi-scan
(SADABS; Bruker, 2001)
h = 711
Tmin = 1.9, Tmax = 28.9k = 1212
5935 measured reflectionsl = 1313
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.027Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.057H-atom parameters constrained
S = 0.99 w = 1/[σ2(Fo2) + (0.0238P)2]
where P = (Fo2 + 2Fc2)/3
4037 reflections(Δ/σ)max = 0.001
262 parametersΔρmax = 0.35 e Å3
0 restraintsΔρmin = 0.35 e Å3
Crystal data top
[CdI2(C18H12N6S2)]γ = 97.726 (1)°
Mr = 742.69V = 1166.81 (15) Å3
Triclinic, P1Z = 2
a = 10.0145 (7) ÅMo Kα radiation
b = 10.7294 (8) ŵ = 3.78 mm1
c = 11.7217 (9) ÅT = 298 K
α = 93.133 (1)°0.20 × 0.15 × 0.12 mm
β = 109.886 (1)°
Data collection top
Bruker APEXII CCD area-detector
diffractometer
4037 independent reflections
Absorption correction: multi-scan
(SADABS; Bruker, 2001)
3073 reflections with I > 2σ(I)
Tmin = 1.9, Tmax = 28.9Rint = 0.015
5935 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.0270 restraints
wR(F2) = 0.057H-atom parameters constrained
S = 0.99Δρmax = 0.35 e Å3
4037 reflectionsΔρmin = 0.35 e Å3
262 parameters
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
I21.04050 (3)0.30244 (3)0.04759 (3)0.06234 (11)
I10.58853 (3)0.01728 (3)0.20478 (3)0.07768 (13)
Cd10.80005 (3)0.17348 (3)0.02843 (3)0.05367 (11)
S10.66738 (13)0.72678 (11)0.58132 (11)0.0647 (3)
S20.83801 (13)0.63432 (12)0.62502 (11)0.0666 (3)
N10.6891 (4)0.3069 (3)0.0542 (3)0.0487 (9)
N20.6043 (3)0.5841 (3)0.3679 (3)0.0466 (8)
N30.4190 (4)0.6770 (3)0.4080 (4)0.0593 (10)
C60.5105 (4)0.5314 (3)0.2591 (4)0.0426 (10)
C40.7136 (4)0.4798 (4)0.2009 (4)0.0526 (11)
H4A0.77360.54650.25650.063*
C90.5529 (4)0.6526 (4)0.4357 (4)0.0508 (11)
C80.3282 (5)0.6238 (4)0.2986 (5)0.0618 (13)
H8A0.23340.63790.27390.074*
C30.7684 (4)0.4046 (4)0.1332 (4)0.0523 (11)
H3B0.86550.42380.14370.063*
C50.5695 (4)0.4544 (3)0.1849 (4)0.0423 (10)
C20.5492 (5)0.2843 (4)0.0378 (4)0.0632 (13)
H2B0.49110.21780.01910.076*
C10.4868 (5)0.3542 (4)0.1005 (4)0.0606 (13)
H1A0.38890.33430.08640.073*
C70.3683 (4)0.5492 (4)0.2207 (4)0.0530 (11)
H7A0.30260.51220.14540.064*
N50.9147 (3)0.7871 (3)0.4735 (3)0.0474 (8)
C131.0157 (4)0.8354 (4)0.4271 (4)0.0493 (11)
C140.9704 (4)0.9207 (4)0.3321 (4)0.0459 (10)
C100.9551 (5)0.7070 (4)0.5546 (4)0.0571 (12)
N41.0789 (5)0.6629 (4)0.5948 (4)0.0815 (13)
C181.0671 (4)0.9895 (4)0.2893 (4)0.0548 (12)
H18A1.16510.98780.32520.066*
C150.8267 (5)0.9313 (4)0.2767 (5)0.0637 (13)
H15A0.75760.88890.30360.076*
C121.1494 (5)0.7979 (5)0.4649 (5)0.0737 (14)
H12A1.21980.83060.43450.088*
C111.1754 (6)0.7115 (6)0.5484 (5)0.0934 (18)
H11A1.26500.68560.57360.112*
C171.0191 (5)1.0597 (4)0.1950 (5)0.0566 (12)
H17A1.08641.10440.16760.068*
N60.8813 (4)1.0678 (3)0.1399 (3)0.0537 (9)
C160.7870 (5)1.0040 (4)0.1829 (5)0.0697 (14)
H16A0.69001.00970.14700.084*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
I20.04535 (17)0.0650 (2)0.0747 (2)0.00692 (14)0.02573 (16)0.00033 (16)
I10.04633 (19)0.0866 (2)0.0967 (3)0.00948 (16)0.03348 (19)0.0232 (2)
Cd10.04412 (19)0.05401 (19)0.0674 (3)0.00516 (14)0.02683 (18)0.00403 (16)
S10.0556 (7)0.0817 (8)0.0595 (9)0.0022 (6)0.0296 (7)0.0090 (7)
S20.0583 (8)0.0876 (9)0.0536 (9)0.0064 (6)0.0201 (6)0.0158 (7)
N10.043 (2)0.051 (2)0.053 (2)0.0078 (17)0.0185 (18)0.0044 (18)
N20.0358 (19)0.053 (2)0.053 (2)0.0038 (16)0.0198 (18)0.0010 (17)
N30.048 (2)0.063 (2)0.073 (3)0.0126 (19)0.028 (2)0.005 (2)
C60.036 (2)0.040 (2)0.053 (3)0.0036 (18)0.017 (2)0.009 (2)
C40.043 (2)0.056 (3)0.056 (3)0.003 (2)0.016 (2)0.002 (2)
C90.043 (3)0.053 (2)0.059 (3)0.003 (2)0.024 (2)0.007 (2)
C80.042 (3)0.066 (3)0.085 (4)0.019 (2)0.028 (3)0.014 (3)
C30.032 (2)0.066 (3)0.059 (3)0.002 (2)0.020 (2)0.005 (2)
C50.037 (2)0.044 (2)0.049 (3)0.0089 (18)0.019 (2)0.010 (2)
C20.043 (3)0.063 (3)0.076 (4)0.003 (2)0.020 (3)0.019 (3)
C10.041 (2)0.064 (3)0.074 (4)0.002 (2)0.021 (2)0.008 (3)
C70.043 (3)0.059 (3)0.053 (3)0.009 (2)0.011 (2)0.004 (2)
N50.0379 (19)0.061 (2)0.042 (2)0.0099 (16)0.0132 (17)0.0014 (18)
C130.045 (2)0.055 (2)0.050 (3)0.007 (2)0.021 (2)0.009 (2)
C140.038 (2)0.054 (2)0.047 (3)0.0098 (19)0.018 (2)0.004 (2)
C100.045 (3)0.077 (3)0.050 (3)0.014 (2)0.016 (2)0.002 (3)
N40.066 (3)0.125 (4)0.070 (3)0.038 (3)0.033 (3)0.037 (3)
C180.036 (2)0.061 (3)0.068 (4)0.004 (2)0.022 (2)0.000 (2)
C150.040 (3)0.087 (3)0.075 (4)0.008 (2)0.031 (3)0.024 (3)
C120.047 (3)0.113 (4)0.076 (4)0.027 (3)0.033 (3)0.024 (3)
C110.059 (3)0.154 (6)0.087 (5)0.052 (4)0.034 (3)0.046 (4)
C170.043 (3)0.054 (3)0.077 (4)0.001 (2)0.029 (3)0.003 (3)
N60.046 (2)0.054 (2)0.069 (3)0.0120 (17)0.028 (2)0.0135 (18)
C160.038 (3)0.091 (4)0.092 (4)0.017 (2)0.033 (3)0.034 (3)
Geometric parameters (Å, º) top
I2—Cd12.6962 (4)C2—H2B0.9300
I1—Cd12.6938 (5)C1—H1A0.9300
Cd1—N12.287 (3)C7—H7A0.9300
Cd1—N6i2.290 (4)N5—C101.314 (5)
S1—C91.771 (4)N5—C131.360 (5)
S1—S22.0205 (19)C13—C121.383 (6)
S2—C101.774 (4)C13—C141.470 (6)
N1—C31.326 (5)C14—C181.383 (5)
N1—C21.334 (5)C14—C151.386 (6)
N2—C91.325 (4)C10—N41.330 (6)
N2—C61.338 (5)N4—C111.325 (6)
N3—C91.334 (5)C18—C171.359 (6)
N3—C81.336 (5)C18—H18A0.9300
C6—C71.383 (5)C15—C161.362 (6)
C6—C51.480 (5)C15—H15A0.9300
C4—C51.378 (5)C12—C111.370 (7)
C4—C31.388 (5)C12—H12A0.9300
C4—H4A0.9300C11—H11A0.9300
C8—C71.376 (5)C17—N61.326 (5)
C8—H8A0.9300C17—H17A0.9300
C3—H3B0.9300N6—C161.343 (5)
C5—C11.381 (5)N6—Cd1ii2.290 (4)
C2—C11.367 (5)C16—H16A0.9300
N1—Cd1—N6i96.12 (11)C5—C1—H1A120.0
N1—Cd1—I1106.24 (9)C8—C7—C6117.1 (4)
N6i—Cd1—I1108.88 (8)C8—C7—H7A121.4
N1—Cd1—I2109.95 (8)C6—C7—H7A121.4
N6i—Cd1—I2104.57 (8)C10—N5—C13115.5 (4)
I1—Cd1—I2126.810 (15)N5—C13—C12119.8 (4)
C9—S1—S2104.45 (14)N5—C13—C14116.3 (4)
C10—S2—S1106.08 (18)C12—C13—C14123.7 (4)
C3—N1—C2117.0 (3)C18—C14—C15116.6 (4)
C3—N1—Cd1119.2 (2)C18—C14—C13122.1 (4)
C2—N1—Cd1123.3 (3)C15—C14—C13121.3 (4)
C9—N2—C6116.3 (3)N5—C10—N4129.3 (4)
C9—N3—C8114.5 (3)N5—C10—S2121.9 (3)
N2—C6—C7121.2 (3)N4—C10—S2108.7 (4)
N2—C6—C5115.6 (3)C11—N4—C10114.0 (5)
C7—C6—C5123.3 (4)C17—C18—C14120.1 (4)
C5—C4—C3119.2 (4)C17—C18—H18A120.0
C5—C4—H4A120.4C14—C18—H18A120.0
C3—C4—H4A120.4C16—C15—C14119.9 (4)
N2—C9—N3127.8 (4)C16—C15—H15A120.1
N2—C9—S1120.2 (3)C14—C15—H15A120.1
N3—C9—S1112.0 (3)C11—C12—C13118.2 (4)
N3—C8—C7123.1 (4)C11—C12—H12A120.9
N3—C8—H8A118.4C13—C12—H12A120.9
C7—C8—H8A118.4N4—C11—C12123.1 (5)
N1—C3—C4123.3 (4)N4—C11—H11A118.5
N1—C3—H3B118.4C12—C11—H11A118.5
C4—C3—H3B118.4N6—C17—C18123.5 (4)
C4—C5—C1117.2 (3)N6—C17—H17A118.2
C4—C5—C6119.8 (4)C18—C17—H17A118.2
C1—C5—C6122.9 (3)C17—N6—C16116.9 (4)
N1—C2—C1123.2 (4)C17—N6—Cd1ii123.1 (3)
N1—C2—H2B118.4C16—N6—Cd1ii119.9 (3)
C1—C2—H2B118.4N6—C16—C15123.0 (4)
C2—C1—C5120.0 (4)N6—C16—H16A118.5
C2—C1—H1A120.0C15—C16—H16A118.5
C9—S1—S2—C1084.1 (2)N3—C8—C7—C61.0 (6)
N6i—Cd1—N1—C376.8 (3)N2—C6—C7—C80.5 (6)
I1—Cd1—N1—C3171.5 (3)C5—C6—C7—C8179.6 (4)
I2—Cd1—N1—C331.2 (3)C10—N5—C13—C120.9 (6)
N6i—Cd1—N1—C295.6 (4)C10—N5—C13—C14177.3 (3)
I1—Cd1—N1—C216.2 (4)N5—C13—C14—C18171.0 (3)
I2—Cd1—N1—C2156.5 (3)C12—C13—C14—C1812.8 (6)
C9—N2—C6—C70.4 (5)N5—C13—C14—C1512.1 (5)
C9—N2—C6—C5179.5 (3)C12—C13—C14—C15164.2 (4)
C6—N2—C9—N31.0 (6)C13—N5—C10—N42.6 (7)
C6—N2—C9—S1180.0 (3)C13—N5—C10—S2180.0 (3)
C8—N3—C9—N20.6 (6)S1—S2—C10—N511.3 (4)
C8—N3—C9—S1179.6 (3)S1—S2—C10—N4170.8 (3)
S2—S1—C9—N218.5 (3)N5—C10—N4—C112.6 (8)
S2—S1—C9—N3162.4 (3)S2—C10—N4—C11179.7 (4)
C9—N3—C8—C70.4 (6)C15—C14—C18—C172.1 (6)
C2—N1—C3—C42.3 (6)C13—C14—C18—C17175.0 (4)
Cd1—N1—C3—C4170.5 (3)C18—C14—C15—C161.9 (6)
C5—C4—C3—N11.2 (6)C13—C14—C15—C16175.2 (4)
C3—C4—C5—C10.3 (6)N5—C13—C12—C110.5 (7)
C3—C4—C5—C6178.2 (4)C14—C13—C12—C11175.7 (4)
N2—C6—C5—C426.6 (5)C10—N4—C11—C120.9 (8)
C7—C6—C5—C4153.5 (4)C13—C12—C11—N40.4 (9)
N2—C6—C5—C1151.8 (4)C14—C18—C17—N60.6 (6)
C7—C6—C5—C128.1 (6)C18—C17—N6—C161.2 (6)
C3—N1—C2—C12.0 (7)C18—C17—N6—Cd1ii175.0 (3)
Cd1—N1—C2—C1170.5 (4)C17—N6—C16—C151.4 (7)
N1—C2—C1—C50.6 (7)Cd1ii—N6—C16—C15174.9 (4)
C4—C5—C1—C20.6 (6)C14—C15—C16—N60.1 (7)
C6—C5—C1—C2177.9 (4)
Symmetry codes: (i) x, y1, z; (ii) x, y+1, z.

Experimental details

Crystal data
Chemical formula[CdI2(C18H12N6S2)]
Mr742.69
Crystal system, space groupTriclinic, P1
Temperature (K)298
a, b, c (Å)10.0145 (7), 10.7294 (8), 11.7217 (9)
α, β, γ (°)93.133 (1), 109.886 (1), 97.726 (1)
V3)1166.81 (15)
Z2
Radiation typeMo Kα
µ (mm1)3.78
Crystal size (mm)0.20 × 0.15 × 0.12
Data collection
DiffractometerBruker APEXII CCD area-detector
diffractometer
Absorption correctionMulti-scan
(SADABS; Bruker, 2001)
Tmin, Tmax1.9, 28.9
No. of measured, independent and
observed [I > 2σ(I)] reflections
5935, 4037, 3073
Rint0.015
(sin θ/λ)max1)0.595
Refinement
R[F2 > 2σ(F2)], wR(F2), S 0.027, 0.057, 0.99
No. of reflections4037
No. of parameters262
H-atom treatmentH-atom parameters constrained
Δρmax, Δρmin (e Å3)0.35, 0.35

Computer programs: APEX2 (Bruker, 2007), SAINT-Plus (Bruker, 2007), SHELXS97 (Sheldrick, 2008), SHELXL97 (Sheldrick, 2008), SHELXTL (Sheldrick, 2008).

 

Acknowledgements

The author acknowledges the finanical support from the China Postdoctoral Reseach Fund (grant No. 20070411010).

References

First citationBruker (2001). SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.  Google Scholar
First citationBruker (2007). APEX2 and SAINT-Plus. Bruker AXS Inc., Madison, Wisconsin, USA.  Google Scholar
First citationHorikoshi, R. & Mochida, T. (2006). Coord. Chem. Rev. 250, 2595–2609.  Web of Science CrossRef CAS Google Scholar
First citationSheldrick, G. M. (2008). Acta Cryst. A64, 112–122.  Web of Science CrossRef CAS IUCr Journals Google Scholar
First citationZhu, H. B., Wang, H., Kong, F., Gou, S. H. & Sun, Y. M. (2009). J. Mol. Struct. 936, 99–103.  Web of Science CSD CrossRef CAS Google Scholar

This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.

Journal logoCRYSTALLOGRAPHIC
COMMUNICATIONS
ISSN: 2056-9890
Follow Acta Cryst. E
Sign up for e-alerts
Follow Acta Cryst. on Twitter
Follow us on facebook
Sign up for RSS feeds