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Acta Cryst. (2010). E66, m41    [ doi:10.1107/S1600536809052325 ]

catena-Poly[[di-[mu]-iodido-dicopper(I)(Cu-Cu)]bis([mu]-4,4'-di-3-pyridyl-2,2'-disulfanediyldipyrimidine)]

H.-B. Zhu

Abstract top

The title complex, [Cu2I2(C18H12N6S2)2]n, contains a Cu2I2 core with a Cu-Cu distance of 2.6935 (14) Å. The CuI atom is coordinated by two bridging 4,4'-di-3-pyridyl-2,2'-disulfanediyldipyrimidine ligands and two bridging I atoms, forming a double chain.

Comment top

In recent years, heterocyclic disulfide ligands have received increasing attention because of their conformationally defined dihedral angle (Horikoshi & Mochida, 2006). As continuation of our previous research (Zhu et al., 2009), we report here a copper(I) coordination polymer with a 2,2'-dithiobis(3-pyridin-4-ylpyrimidine) (L) ligand.

The CuI atom in the title complex has a tetrahedral coordination geometry completed by two N atoms from two different L ligands and two bridging I atoms (Fig. 1 and Table 1). The C—S—S—C torsion angle of 81.2 (2)° in L is almost identical with the free molecule (Ji et al., 2009). Alternative linkings of one Cu2I2 core and two bridging L ligands generate a one-dimensional double chain (Fig. 2).

Related literature top

For coordination polymers with 4,4'-dipyridinedisulfide, see: Horikoshi & Mochida (2006). For coordination polymers with 2,2'-dithiobis(4-pyridin-4-yl-pyrimidine), see: Zhu et al. (2009). For the structure of free 2,2'-dithiobis(3-pyridin-4-yl-pyrimidine), see: Ji et al. (2009).

Experimental top

A CH2Cl2 solution (5 ml) of ligand L (0.1 mmol) was slowly added into a CuI (0.1 mmol) solution in acetonitrile (10 ml). The mixture was kept on standing for 3 d to give single crystals suitable for X-ray diffraction analysis.

Refinement top

H atoms were positioned geometrically and refined as riding atoms, with C—H = 0.93 Å and Uiso(H) = 1.2Ueq(C). The highest residual electron density was found 0.98 Å from I1 and the deepest hole 0.92 Å from I1.

Computing details top

Data collection: APEX2 (Bruker, 2007); cell refinement: SAINT-Plus (Bruker, 2007); data reduction: SAINT-Plus (Bruker, 2007); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008) and DIAMOND (Brandenburg, 1999); software used to prepare material for publication: SHELXTL (Sheldrick, 2008).

Figures top
[Figure 1] Fig. 1. The structure of the title compound with 30% probability displacement ellipsoids. H atoms have been omitted for clarity. [Symmetry codes: (i) -x + 1, -y + 2, -z; (ii) x, y + 1, z - 1.]
[Figure 2] Fig. 2. The one-dimensional double chain viewed along the a axis.
catena-Poly[[di-µ-iodido-dicopper(I)(Cu—Cu)]bis(µ- 4,4'-di-3-pyridyl-2,2'-disulfanediyldipyrimidine)] top
Crystal data top
[Cu2I2(C18H12N6S2)2]Z = 1
Mr = 1133.86F(000) = 552
Triclinic, P1Dx = 1.839 Mg m−3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71073 Å
a = 8.5561 (6) ÅCell parameters from 3568 reflections
b = 10.7702 (8) Åθ = 2.3–25.5°
c = 11.9045 (8) ŵ = 2.80 mm−1
α = 98.110 (1)°T = 298 K
β = 107.193 (1)°Block, yellow
γ = 96.449 (1)°0.19 × 0.15 × 0.12 mm
V = 1023.66 (13) Å3
Data collection top
Bruker APEXII CCD
diffractometer		3568 independent reflections
Radiation source: fine-focus sealed tube2956 reflections with I > 2σ(I)
graphiteRint = 0.097
φ and ω scansθmax = 25.0°, θmin = 1.8°
Absorption correction: multi-scan
(SADABS; Bruker, 2001)		h = −7→10
Tmin = 0.611, Tmax = 0.715k = −12→12
5395 measured reflectionsl = −14→13
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.041Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.108H-atom parameters constrained
S = 0.99 w = 1/[σ2(Fo2) + (0.0541P)2]
where P = (Fo2 + 2Fc2)/3
3568 reflections(Δ/σ)max = 0.001
253 parametersΔρmax = 1.28 e Å−3
0 restraintsΔρmin = −1.03 e Å−3
Crystal data top
[Cu2I2(C18H12N6S2)2]γ = 96.449 (1)°
Mr = 1133.86V = 1023.66 (13) Å3
Triclinic, P1Z = 1
a = 8.5561 (6) ÅMo Kα radiation
b = 10.7702 (8) ŵ = 2.80 mm−1
c = 11.9045 (8) ÅT = 298 K
α = 98.110 (1)°0.19 × 0.15 × 0.12 mm
β = 107.193 (1)°
Data collection top
Bruker APEXII CCD
diffractometer		3568 independent reflections
Absorption correction: multi-scan
(SADABS; Bruker, 2001)		2956 reflections with I > 2σ(I)
Tmin = 0.611, Tmax = 0.715Rint = 0.097
5395 measured reflectionsθmax = 25.0°
Refinement top
R[F2 > 2σ(F2)] = 0.041H-atom parameters constrained
wR(F2) = 0.108Δρmax = 1.28 e Å−3
S = 0.99Δρmin = −1.03 e Å−3
3568 reflectionsAbsolute structure: ?
253 parametersFlack parameter: ?
0 restraintsRogers parameter: ?
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
I10.31696 (4)0.97725 (3)0.10525 (3)0.04697 (15)
Cu10.38873 (9)0.92391 (6)−0.09670 (6)0.0503 (2)
S10.13540 (17)0.55124 (12)0.27577 (10)0.0447 (3)
S20.02067 (16)0.43336 (14)0.35509 (12)0.0498 (3)
N20.2094 (5)0.5182 (3)0.0809 (3)0.0340 (8)
C50.3021 (5)0.5258 (4)−0.0900 (4)0.0328 (10)
N30.0948 (5)0.3267 (4)0.1271 (4)0.0426 (10)
N10.3815 (5)0.7322 (4)−0.1296 (3)0.0387 (9)
C90.1455 (5)0.4513 (4)0.1466 (4)0.0340 (10)
N50.1235 (5)0.2820 (4)0.4999 (3)0.0381 (9)
C10.3142 (6)0.6574 (4)−0.0705 (4)0.0356 (10)
H1A0.27280.6955−0.01270.043*
C60.2284 (5)0.4523 (4)−0.0183 (4)0.0330 (10)
C100.1797 (6)0.3566 (5)0.4357 (4)0.0392 (11)
C30.4346 (6)0.5483 (5)−0.2380 (4)0.0436 (11)
H3B0.47720.5130−0.29630.052*
C130.2302 (6)0.2187 (4)0.5638 (4)0.0381 (10)
C120.3936 (6)0.2331 (5)0.5625 (4)0.0480 (13)
H12A0.47040.18940.60670.058*
C40.3639 (6)0.4719 (5)−0.1776 (4)0.0411 (11)
H4A0.35720.3842−0.19510.049*
N40.3312 (5)0.3777 (4)0.4277 (3)0.0453 (10)
C110.4371 (6)0.3147 (5)0.4933 (5)0.0515 (13)
H11A0.54610.32610.49250.062*
C20.4419 (6)0.6772 (5)−0.2117 (4)0.0418 (11)
H2B0.49090.7284−0.25280.050*
C80.1115 (6)0.2636 (5)0.0281 (5)0.0457 (12)
H8A0.07660.17610.00870.055*
C70.1775 (6)0.3213 (4)−0.0466 (4)0.0416 (11)
H7A0.18830.2739−0.11480.050*
C140.1671 (6)0.1341 (4)0.6336 (4)0.0380 (10)
C15−0.0011 (6)0.1112 (5)0.6209 (4)0.0475 (12)
H15A−0.07610.15000.56910.057*
C16−0.0545 (7)0.0301 (5)0.6864 (5)0.0532 (14)
H16A−0.16630.01410.67960.064*
C180.2701 (7)0.0733 (5)0.7125 (4)0.0456 (12)
H18A0.38270.08800.72170.055*
C170.0554 (7)−0.0264 (5)0.7604 (4)0.0503 (13)
H17A0.0161−0.08250.80230.060*
N60.2191 (5)−0.0053 (4)0.7765 (3)0.0442 (10)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
I10.0504 (2)0.0489 (2)0.0526 (2)0.00536 (15)0.02987 (17)0.01773 (16)
Cu10.0647 (4)0.0437 (4)0.0576 (4)0.0113 (3)0.0319 (3)0.0285 (3)
S10.0595 (8)0.0464 (7)0.0346 (6)0.0117 (6)0.0179 (6)0.0187 (5)
S20.0478 (7)0.0725 (9)0.0424 (7)0.0181 (7)0.0204 (6)0.0338 (7)
N20.039 (2)0.034 (2)0.0308 (19)0.0039 (16)0.0112 (16)0.0143 (16)
C50.031 (2)0.036 (2)0.031 (2)0.0029 (19)0.0078 (18)0.0140 (19)
N30.045 (2)0.040 (2)0.049 (2)0.0049 (18)0.0167 (19)0.0225 (19)
N10.044 (2)0.038 (2)0.038 (2)0.0031 (17)0.0182 (18)0.0159 (17)
C90.035 (2)0.040 (3)0.028 (2)0.008 (2)0.0081 (19)0.0147 (19)
N50.042 (2)0.046 (2)0.0293 (19)0.0054 (18)0.0114 (17)0.0156 (17)
C10.042 (3)0.035 (2)0.036 (2)0.007 (2)0.018 (2)0.012 (2)
C60.033 (2)0.034 (2)0.033 (2)0.0050 (19)0.0091 (19)0.0131 (19)
C100.044 (3)0.045 (3)0.030 (2)0.004 (2)0.012 (2)0.012 (2)
C30.046 (3)0.053 (3)0.036 (2)0.008 (2)0.018 (2)0.008 (2)
C130.046 (3)0.040 (3)0.029 (2)0.004 (2)0.011 (2)0.012 (2)
C120.041 (3)0.060 (3)0.047 (3)0.012 (2)0.010 (2)0.030 (3)
C40.046 (3)0.039 (3)0.039 (3)0.005 (2)0.015 (2)0.008 (2)
N40.043 (2)0.057 (3)0.039 (2)0.006 (2)0.0127 (18)0.021 (2)
C110.038 (3)0.069 (4)0.051 (3)0.001 (3)0.013 (2)0.027 (3)
C20.046 (3)0.048 (3)0.036 (3)0.000 (2)0.018 (2)0.016 (2)
C80.051 (3)0.034 (3)0.052 (3)0.004 (2)0.015 (2)0.014 (2)
C70.056 (3)0.031 (2)0.039 (3)0.006 (2)0.017 (2)0.010 (2)
C140.046 (3)0.037 (2)0.033 (2)0.005 (2)0.016 (2)0.010 (2)
C150.046 (3)0.059 (3)0.040 (3)0.004 (2)0.014 (2)0.017 (2)
C160.050 (3)0.070 (4)0.045 (3)0.001 (3)0.022 (2)0.018 (3)
C180.049 (3)0.048 (3)0.045 (3)0.004 (2)0.018 (2)0.021 (2)
C170.064 (3)0.048 (3)0.047 (3)−0.002 (3)0.029 (3)0.018 (2)
N60.054 (3)0.042 (2)0.041 (2)0.0064 (19)0.0178 (19)0.0175 (18)
Geometric parameters (Å, °) top
Cu1—I12.6550 (7)C3—H3B0.9300
Cu1—I1i2.6579 (8)C13—C121.394 (7)
Cu1—N12.037 (4)C13—C141.477 (6)
Cu1—N6ii2.060 (4)C12—C111.379 (7)
Cu1—Cu1i2.6935 (14)C12—H12A0.9300
S1—C91.779 (5)C4—H4A0.9300
S1—S22.0183 (17)N4—C111.327 (6)
S2—C101.778 (5)C11—H11A0.9300
N2—C91.323 (5)C2—H2B0.9300
N2—C61.352 (6)C8—C71.367 (6)
C5—C11.390 (6)C8—H8A0.9300
C5—C41.389 (6)C7—H7A0.9300
C5—C61.466 (6)C14—C181.379 (7)
N3—C91.329 (6)C14—C151.392 (7)
N3—C81.329 (6)C15—C161.376 (7)
N1—C21.333 (6)C15—H15A0.9300
N1—C11.330 (5)C16—C171.349 (7)
N5—C131.324 (6)C16—H16A0.9300
N5—C101.328 (6)C18—N61.336 (6)
C1—H1A0.9300C18—H18A0.9300
C6—C71.391 (6)C17—N61.344 (7)
C10—N41.325 (6)C17—H17A0.9300
C3—C21.370 (7)N6—Cu1iii2.060 (4)
C3—C41.368 (6)
Cu1—I1—Cu1i60.92 (3)C12—C13—C14123.0 (4)
N1—Cu1—N6ii115.68 (16)C11—C12—C13117.4 (4)
N1—Cu1—I1106.36 (10)C11—C12—H12A121.3
N6ii—Cu1—I1106.25 (12)C13—C12—H12A121.3
N1—Cu1—I1i105.02 (11)C3—C4—C5119.8 (4)
N6ii—Cu1—I1i104.97 (12)C3—C4—H4A120.1
I1—Cu1—I1i119.08 (3)C5—C4—H4A120.1
N1—Cu1—Cu1i122.23 (11)C10—N4—C11113.9 (4)
N6ii—Cu1—Cu1i122.06 (12)N4—C11—C12123.3 (5)
I1—Cu1—Cu1i59.59 (2)N4—C11—H11A118.3
I1i—Cu1—Cu1i59.49 (3)C12—C11—H11A118.3
C9—S1—S2104.18 (16)N1—C2—C3122.6 (4)
C10—S2—S1104.60 (17)N1—C2—H2B118.7
C9—N2—C6116.6 (4)C3—C2—H2B118.7
C1—C5—C4116.6 (4)C7—C8—N3123.1 (4)
C1—C5—C6119.6 (4)C7—C8—H8A118.5
C4—C5—C6123.8 (4)N3—C8—H8A118.5
C9—N3—C8114.2 (4)C8—C7—C6118.6 (4)
C2—N1—C1117.8 (4)C8—C7—H7A120.7
C2—N1—Cu1121.4 (3)C6—C7—H7A120.7
C1—N1—Cu1120.8 (3)C18—C14—C15117.0 (4)
N2—C9—N3128.4 (4)C18—C14—C13122.1 (4)
N2—C9—S1110.9 (3)C15—C14—C13120.8 (4)
N3—C9—S1120.7 (3)C14—C15—C16118.8 (5)
C13—N5—C10116.9 (4)C14—C15—H15A120.6
N1—C1—C5123.9 (4)C16—C15—H15A120.6
N1—C1—H1A118.0C17—C16—C15120.0 (5)
C5—C1—H1A118.0C17—C16—H16A120.0
N2—C6—C7119.1 (4)C15—C16—H16A120.0
N2—C6—C5116.7 (4)N6—C18—C14124.5 (5)
C7—C6—C5124.2 (4)N6—C18—H18A117.8
N4—C10—N5128.4 (4)C14—C18—H18A117.8
N4—C10—S2120.6 (3)C16—C17—N6123.1 (5)
N5—C10—S2111.1 (3)C16—C17—H17A118.5
C2—C3—C4119.3 (4)N6—C17—H17A118.5
C2—C3—H3B120.4C18—N6—C17116.6 (4)
C4—C3—H3B120.4C18—N6—Cu1iii120.4 (4)
N5—C13—C12120.0 (4)C17—N6—Cu1iii122.7 (3)
N5—C13—C14117.0 (4)
Cu1i—I1—Cu1—N1118.18 (12)C10—N5—C13—C120.7 (7)
Cu1i—I1—Cu1—N6ii−118.04 (12)C10—N5—C13—C14−179.0 (4)
Cu1i—I1—Cu1—I1i0.0N5—C13—C12—C110.1 (7)
C9—S1—S2—C1081.1 (2)C14—C13—C12—C11179.7 (4)
N6ii—Cu1—N1—C275.1 (4)C2—C3—C4—C5−0.6 (7)
I1—Cu1—N1—C2−167.2 (3)C1—C5—C4—C31.1 (6)
I1i—Cu1—N1—C2−40.1 (4)C6—C5—C4—C3−178.3 (4)
Cu1i—Cu1—N1—C2−103.2 (3)N5—C10—N4—C110.0 (8)
N6ii—Cu1—N1—C1−104.0 (4)S2—C10—N4—C11179.6 (4)
I1—Cu1—N1—C113.7 (4)C10—N4—C11—C120.8 (8)
I1i—Cu1—N1—C1140.8 (3)C13—C12—C11—N4−0.9 (8)
Cu1i—Cu1—N1—C177.7 (4)C1—N1—C2—C31.0 (7)
C6—N2—C9—N3−1.0 (7)Cu1—N1—C2—C3−178.1 (4)
C6—N2—C9—S1178.0 (3)C4—C3—C2—N1−0.5 (7)
C8—N3—C9—N2−0.2 (7)C9—N3—C8—C71.0 (7)
C8—N3—C9—S1−179.1 (3)N3—C8—C7—C6−0.6 (8)
S2—S1—C9—N2176.0 (3)N2—C6—C7—C8−0.7 (7)
S2—S1—C9—N3−4.8 (4)C5—C6—C7—C8179.6 (4)
C2—N1—C1—C5−0.5 (7)N5—C13—C14—C18−173.4 (4)
Cu1—N1—C1—C5178.7 (3)C12—C13—C14—C186.9 (7)
C4—C5—C1—N1−0.5 (7)N5—C13—C14—C157.5 (7)
C6—C5—C1—N1178.9 (4)C12—C13—C14—C15−172.2 (5)
C9—N2—C6—C71.4 (6)C18—C14—C15—C16−0.2 (7)
C9—N2—C6—C5−178.8 (4)C13—C14—C15—C16178.9 (4)
C1—C5—C6—N2−14.3 (6)C14—C15—C16—C17−0.6 (8)
C4—C5—C6—N2165.0 (4)C15—C14—C18—N60.0 (7)
C1—C5—C6—C7165.5 (4)C13—C14—C18—N6−179.1 (4)
C4—C5—C6—C7−15.2 (7)C15—C16—C17—N61.6 (8)
C13—N5—C10—N4−0.8 (7)C14—C18—N6—C170.9 (7)
C13—N5—C10—S2179.6 (3)C14—C18—N6—Cu1iii−174.0 (4)
S1—S2—C10—N4−4.1 (4)C16—C17—N6—C18−1.7 (8)
S1—S2—C10—N5175.5 (3)C16—C17—N6—Cu1iii173.0 (4)
Symmetry codes: (i) −x+1, −y+2, −z; (ii) x, y+1, z−1; (iii) x, y−1, z+1.
Table 1
Selected geometric parameters (Å) top
Cu1—I12.6550 (7)Cu1—N12.037 (4)
Cu1—I1i2.6579 (8)Cu1—N6ii2.060 (4)
Symmetry codes: (i) −x+1, −y+2, −z; (ii) x, y+1, z−1.
Acknowledgements top

The author acknowledges finanical support from the China Postdoctoral Reseach Fund (20070411010).

references
References top

Brandenburg, K. (1999). DIAMOND. Crystal Impact GbR, Bonn, Germany.

Bruker (2001). SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.

Bruker (2007). APEX2 and SAINT-Plus. Bruker AXS Inc., Madison, Wisconsin, USA.

Horikoshi, R. & Mochida, T. (2006). Coord. Chem. Rev. 250, 2595–2609.

Ji, J.-F., Li, L. & Zhu, H.-B. (2009). Acta Cryst. E65, o1253.

Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122.

Zhu, H.-B., Wang, H., Kong, F., Gou, S.-H. & Sun, Y.-M. (2009). J. Mol. Struct. 936, 99–103.