catena-Poly[zinc(II)-μ3-{hydrogen [1-hydr­oxy-2-(3-pyridinio)ethane-1,1-di­yl]diphospho­nato}]

Huang, X.; Liu, Z.; Huang, C.; Wang, Y.

doi:10.1107/S1600536809052702

metal-organic compounds

CRYSTALLOGRAPHIC
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ISSN: 2056-9890

Volume 66| Part 1| January 2010| Pages m59-m60

doi:10.1107/S1600536809052702

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catena-Poly[zinc(II)-μ₃-{hydrogen [1-hydroxy-2-(3-pyridinio)ethane-1,1-diyl]diphosphonato}]

Xihe Huang,^a ^* Zhongqian Liu,^a Changcang Huang ^a and Yubo Wang ^a

^aDepartment of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, People's Republic of China
^*Correspondence e-mail: xhhuang@fzu.edu.cn

(Received 4 November 2009; accepted 8 December 2009; online 12 December 2009)

In the polymeric title compound, [Zn(C₇H₉NO₇P₂)]_n, the zinc(II) centre displays a tetrahedral coordination geometry provided by four O atoms from three different phosphonate groups. The crystal structure consists of ladder chains parallel to the b axis built up from vertex-sharing of ZnO₄ and PO₃C tetrahedra. The chains are linked by strong intra- and interchain O—H⋯O and N—H⋯O hydrogen bonds, forming a three-dimensional supramolecular assembly.

Related literature

For the chemistry and applications of phosphonate metal derivatives, see: Clearfield (1998 ); Cheetham et al. (1999 ); Maeda (2004 ); Gossman et al. (2003 ); Redman-Furey et al. (2005 ); Mao et al. (2006 ); Stahl et al. (2006 ); Zhu et al. (2000 ); Burkholder et al. (2003 ); Bauer et al. (2007 ); Du et al. (2007 ). For examples of structure types exhibited by phosphonate metal derivatives, see: Fu et al. (2006 ); Yang et al. (2007 ). For related structures, see: Zhang & Zheng (2008 ); Zhang, Gao & Zheng (2007 ); Zhang, Bao & Zheng (2007 ); Hu et al. (2008 ).

Experimental

Crystal data

[Zn(C₇H₉NO₇P₂)]
M_r = 346.46
Monoclinic, P 2₁ /n
a = 13.609 (3) Å
b = 5.4809 (11) Å
c = 14.818 (3) Å
β = 101.21 (3)°
V = 1084.2 (4) Å³
Z = 4
Mo Kα radiation
μ = 2.59 mm⁻¹
T = 293 K
0.20 × 0.12 × 0.08 mm

Data collection

Rigaku Mercury CCD area-detector diffractometer
Absorption correction: multi-scan (RAPID-AUTO; Rigaku, 1998 ) T_min = 0.626, T_max = 0.820
8250 measured reflections
2519 independent reflections
2473 reflections with I > 2σ(I)
R_int = 0.025

Refinement

R[F² > 2σ(F²)] = 0.026
wR(F²) = 0.061
S = 1.04
2519 reflections
163 parameters
H-atom parameters constrained
Δρ_max = 0.35 e Å⁻³
Δρ_min = −0.32 e Å⁻³

Table 1
Selected bond lengths (Å)

Zn1—O5ⁱ	1.8791 (16)
Zn1—O2	1.9121 (15)
Zn1—O4ⁱⁱ	1.9243 (15)
Zn1—O1ⁱⁱ	1.9888 (15)
P1—O2	1.4907 (15)
P1—O1	1.5182 (15)
P1—O3	1.5594 (16)
P1—C1	1.843 (2)
P2—O6	1.4953 (15)
P2—O5	1.5115 (16)
P2—O4	1.5236 (15)
P2—C1	1.851 (2)
Symmetry codes: (i) -x+1, -y+1, -z+1; (ii) x, y-1, z.

Table 2
Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
O3—H3⋯O1ⁱⁱⁱ	0.82	1.85	2.637 (2)	161
N1—H1⋯O6^iv	0.86	1.68	2.533 (2)	170
O7—H7⋯O4ⁱⁱ	0.82	1.97	2.758 (2)	163
Symmetry codes: (ii) x, y-1, z; (iii) $[-x+{\script{1\over 2}}, y-{\script{1\over 2}}, -z+{\script{1\over 2}}]$ ; (iv) $[-x+{\script{1\over 2}}, y+{\script{1\over 2}}, -z+{\script{3\over 2}}]$ .

Data collection: CrystalClear (Rigaku, 2002 ); cell refinement: CrystalClear; data reduction: CrystalClear; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL/PC (Sheldrick, 2008); software used to prepare material for publication: SHELXTL/PC.

Supporting information

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536809052702/rz2390sup1.cif

Structure factors: contains datablock I. DOI: 10.1107/S1600536809052702/rz2390Isup2.hkl

checkCIF report

Comment top

The chemistry of metal phosphonates has gained increasing attention because of its potential applications in catalysis, ion exchange, and magnetic materials (Clearfield, 1998; Cheetham et al., 1999; Maeda, 2004). Many efforts have been devoted to the preparation of metal phosphonate materials with new structure types, especially the open-framework and microporous structures (Clearfield, 1998; Fu et al. 2006; Yang et al., 2007). Among these, a promising approach is to modify the organic moieties of the phosphonate ligand RPO₃^2- by other functional groups, such as amino, carboxylate, macrocycle or a second phosphonate group (Zhu et al., 2000; Burkholder et al., 2003; Bauer et al., 2007; Du et al., 2007). Phosphonates based on 1-hydroxyl-1,1-biphosphonic acid, H₂O₃PC(OH)(R)PO₃H₂, such as pamidronate, risedronate, zoledronate and alendronate, are of great research interest because of their applications in therapeutics and as mineral scale inhibitors (Gossman et al., 2003; Redman-Furey et al., 2005; Mao et al., 2006; Stahl et al., 2006). One challenge for studying such materials is that they usually exhibit poor crystallinity, which makes their structural analysis a difficult task. In the case of risedronate acid, (1-hydroxy-2-(3-pyridyl)ethylidene-1,1-diphosphonic acid, abbreviated as H₄hedp), only five metal complexes have hitherto been structurally characterized, namely, Co₃(Hhedp)(H₂O)₄.H₂O (Zhang et al., 2008), Co(H₂hedp)(H₂O) (Zhang, Gao & Zheng, 2007), Gd(H₂hedp)(H₃hedp).2H₂O (Zhang, Bao & Zheng, 2007), Cd(H₂hedp)(H₂O) and Cd₂Cl(Hhedp)(H₂O) (Hu et al., 2008). The hedp ligands of these complexs display a variety of coordination modes. We report herein the synthesis and structural studies of a new metal risedronate complex, Zn(H₂hedp).

The crystal structure of the title complex is built up from one-dimensional covalent zinc phosphonate chains. The asymmetric unit consists of one independent zinc(II) cation and one unique H₂hedp^2- ligand in general position. A detail of the chain structure is illustrated in Fig. 1, showing the coordination geometry of the Zn ion. Every hydrogen phosphonate group of the H₂hedp^2- ligand has two bound oxygen atoms coordinating to the Zn atom and one unbound oxygen atom. The P—O_bound bond lengths fall in the range from 1.4907 (15) to 1.5236 (15) Å. The P1—O3 bond length of 1.5594 (16) Å is consistent with the protonation of this unbound oxygen, while the P2—O6 of 1.4953 (15) Å indicates a P=O double bond. The hydroxyl group attached to the C1 atom linking the two phosphorus atoms is uncoordinated, which involves an intramolecular hydrogen bonding interaction with the O4 atom as hydrogen acceptor (Table 2). As shown in Fig. 1, the H₂hedp^2- ligand adopts a (κ1-κ1)-(κ2)-µ3 bridging mode, i.e. the H₂hedp^2- ligand coordinates one Zn site in a bidentate fashion forming a Zn1ⁱⁱⁱ—O1—P1—C1—P2—O4 six-member chelate ring (symmetry code: (iii) x, 1 + y, z), and two crystallographically equivalent Zn ions in monodentate fashion. The Zn1 atom is tetrahedrally coordinated by four hydrogen phosphonate oxygen atoms from three H₂hedp^2- ligands, with the Zn—O bond lengths in the region of 1.8790 (16)–1.9894 (15) Å, and the O—Zn—O bond angles of 99.06 (6)–117.67 (7)°, respectively (Table 1). Two ZnO₄ tetrahedra are connected by two P2O₃C tetrahedra resulting in a Zn₂P₂ four-membered ring. These rings are further linked by four PO₃C tetrahedra through Zn—O bonds, forming a novel one dimensional ladder chain paralleling to the b axis. As the best of our knowledge, no examples of this ladder structure had been reported up to date. The chains are cross-linked by strong hydrogen bonds with four adjacent chains to form a three-dimensional supramolecular assembly (Fig. 2). Two interchain hydrogen bonding interactions are observed involving the two unbound hydrogen phosphonate oxygen atoms. The pendant O6 atom as a hydrogen acceptor, is responsible of the first inter-chain H-bond with the protonated pyridyl N atom as donators with the O···N distance of 2.533 (2) Å. The second inter-chain H-bond is constructed from the protonated O3 and O1 atom as hydrogen donators and acceptors, respectively, with O···O distances of 2.637 (2) Å.

Related literature top

For the chemistry and applications of phosphonate metal derivatives, see: Clearfield (1998); Cheetham et al. (1999); Maeda (2004); Gossman et al. (2003); Redman-Furey et al. (2005); Mao et al. (2006); Stahl et al. (2006); Zhu et al. (2000); Burkholder et al. (2003); Bauer et al. (2007); Du et al. (2007). For examples of structure types exhibited by phosphonate metal derivatives, see: Fu et al. (2006); Yang et al. (2007). For related structures, see: Zhang et al. (2008); Zhang, Gao & Zheng (2007); Zhang, Bao & Zheng (2007); Hu et al. (2008).

Experimental top

NaH₃hedp.2.5H₂O (0.1405 g, 0.4 mmol) and ZnO (0.0162 g, 0.2 mmol) were dissolved in 6 ml water. The mixture was placed in a 15-ml Teflon-lined stainless steel vessel and heated at 433 K for 72 h. After slowly cooled to room temperature during 24 h, colourless block crystals of the title complex were collected by filtration, washed with distilled water, and dried in air (yield: 45% on the basis of Zn source).

Computing details top

Data collection: CrystalClear (Rigaku, 2002); cell refinement: CrystalClear (Rigaku, 2002); data reduction: CrystalClear (Rigaku, 2002); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL/PC (Sheldrick, 2008); software used to prepare material for publication: SHELXTL/PC (Sheldrick, 2008).

Figures top

	Fig. 1. The structure of the title compound, with the atomic numbering scheme of the asymmetric unit and some symmetry-related atoms (50% probability displacement ellipsoids). All H atoms bonded to C atoms are omitted for clarity. Symmetry codes: (i) 1 - x, -y, 1 - z; (ii) x, -1 + y, z; (iii) x, 1 + y, z.
	Fig. 2. Crystal packing diagram for the title compound. All atoms are shown as isotropic spheres of arbitrary size. H atoms bonded to C atoms are omitted for clarity. The H-bonding interactions are shown as dashed lines.

catena-Poly[zinc(II)-µ₃-{hydrogen [1-hydroxy-2-(3-pyridinio)ethane-1,1-diyl]diphosphonato}] top

Crystal data top

[Zn(C₇H₉NO₇P₂)]	F(000) = 696
M_r = 346.46	D_x = 2.123 Mg m⁻³
Monoclinic, P2₁/n	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2yn	Cell parameters from 3898 reflections
a = 13.609 (3) Å	θ = 3.1–27.7°
b = 5.4809 (11) Å	µ = 2.59 mm⁻¹
c = 14.818 (3) Å	T = 293 K
β = 101.21 (3)°	Block, colorless
V = 1084.2 (4) Å³	0.20 × 0.12 × 0.08 mm
Z = 4

Data collection top

Rigaku Mercury CCD area-detector diffractometer	2519 independent reflections
Radiation source: fine-focus sealed tube	2473 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.025
ω scans	θ_max = 27.7°, θ_min = 3.7°
Absorption correction: multi-scan (RAPID-AUTO; Rigaku, 1998)	h = −17→17
T_min = 0.626, T_max = 0.820	k = −7→7
8250 measured reflections	l = −19→18

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.026	Hydrogen site location: mixed
wR(F²) = 0.061	H-atom parameters constrained
S = 1.04	w = 1/[σ²(F_o²) + (0.0218P)² + 1.6938P] where P = (F_o² + 2F_c²)/3
2519 reflections	(Δ/σ)_max = 0.001
163 parameters	Δρ_max = 0.35 e Å⁻³
0 restraints	Δρ_min = −0.32 e Å⁻³

Crystal data top

[Zn(C₇H₉NO₇P₂)]	V = 1084.2 (4) Å³
M_r = 346.46	Z = 4
Monoclinic, P2₁/n	Mo Kα radiation
a = 13.609 (3) Å	µ = 2.59 mm⁻¹
b = 5.4809 (11) Å	T = 293 K
c = 14.818 (3) Å	0.20 × 0.12 × 0.08 mm
β = 101.21 (3)°

Data collection top

Rigaku Mercury CCD area-detector diffractometer	2519 independent reflections
Absorption correction: multi-scan (RAPID-AUTO; Rigaku, 1998)	2473 reflections with I > 2σ(I)
T_min = 0.626, T_max = 0.820	R_int = 0.025
8250 measured reflections

Refinement top

R[F² > 2σ(F²)] = 0.026	0 restraints
wR(F²) = 0.061	H-atom parameters constrained
S = 1.04	Δρ_max = 0.35 e Å⁻³
2519 reflections	Δρ_min = −0.32 e Å⁻³
163 parameters

Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Zn1	0.412237 (17)	0.25347 (4)	0.425508 (16)	0.01698 (8)
P1	0.29107 (4)	0.76285 (9)	0.37901 (3)	0.01399 (11)
P2	0.36304 (4)	0.92659 (9)	0.57727 (3)	0.01507 (11)
O1	0.32521 (11)	1.0088 (3)	0.34936 (9)	0.0191 (3)
O2	0.36616 (12)	0.5657 (3)	0.37738 (10)	0.0234 (3)
O3	0.18869 (11)	0.6951 (3)	0.31670 (10)	0.0253 (3)
H3	0.1983	0.6398	0.2677	0.038*
O4	0.37845 (11)	1.1832 (3)	0.54302 (10)	0.0201 (3)
O5	0.44985 (11)	0.7562 (3)	0.57500 (12)	0.0259 (3)
O6	0.33324 (11)	0.9324 (3)	0.66920 (9)	0.0234 (3)
O7	0.23742 (11)	0.5508 (3)	0.52251 (10)	0.0211 (3)
H7	0.2870	0.4642	0.5252	0.032*
N1	0.10323 (14)	1.1013 (4)	0.71483 (12)	0.0263 (4)
H1	0.1173	1.2169	0.7545	0.032*
C1	0.25880 (14)	0.7897 (4)	0.49374 (13)	0.0149 (4)
C2	0.16165 (15)	0.9394 (4)	0.48646 (13)	0.0190 (4)
H2A	0.1753	1.1076	0.4727	0.023*
H2B	0.1121	0.8769	0.4357	0.023*
C3	0.11892 (14)	0.9324 (4)	0.57271 (13)	0.0179 (4)
C4	0.06000 (17)	0.7409 (4)	0.59111 (16)	0.0243 (5)
H4A	0.0452	0.6148	0.5487	0.029*
C5	0.02268 (19)	0.7328 (4)	0.67077 (17)	0.0295 (5)
H5A	−0.0182	0.6046	0.6819	0.035*
C6	0.04682 (18)	0.9168 (5)	0.73327 (16)	0.0301 (5)
H6A	0.0239	0.9131	0.7884	0.036*
C7	0.13858 (16)	1.1135 (4)	0.63744 (14)	0.0219 (4)
H7A	0.1772	1.2468	0.6271	0.026*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Zn1	0.01774 (13)	0.01540 (13)	0.01787 (13)	0.00121 (9)	0.00364 (9)	0.00309 (9)
P1	0.0176 (2)	0.0121 (2)	0.0126 (2)	0.00126 (18)	0.00362 (18)	0.00007 (17)
P2	0.0160 (2)	0.0159 (2)	0.0129 (2)	0.00092 (19)	0.00195 (17)	0.00233 (18)
O1	0.0284 (8)	0.0145 (7)	0.0134 (6)	−0.0008 (6)	0.0019 (5)	0.0020 (5)
O2	0.0305 (8)	0.0180 (7)	0.0246 (7)	0.0093 (6)	0.0122 (6)	0.0046 (6)
O3	0.0231 (8)	0.0350 (9)	0.0175 (7)	−0.0036 (7)	0.0033 (6)	−0.0101 (6)
O4	0.0286 (8)	0.0158 (7)	0.0158 (7)	−0.0013 (6)	0.0044 (6)	0.0013 (6)
O5	0.0165 (7)	0.0231 (8)	0.0373 (9)	0.0042 (6)	0.0033 (6)	0.0036 (7)
O6	0.0264 (8)	0.0304 (8)	0.0135 (6)	0.0012 (7)	0.0040 (6)	0.0025 (6)
O7	0.0232 (7)	0.0145 (7)	0.0280 (8)	0.0001 (6)	0.0108 (6)	0.0037 (6)
N1	0.0304 (10)	0.0289 (10)	0.0197 (9)	0.0020 (8)	0.0050 (7)	−0.0083 (8)
C1	0.0169 (9)	0.0137 (9)	0.0144 (9)	0.0009 (7)	0.0040 (7)	0.0007 (7)
C2	0.0181 (9)	0.0222 (10)	0.0166 (9)	0.0047 (8)	0.0030 (7)	−0.0022 (8)
C3	0.0157 (9)	0.0216 (10)	0.0158 (9)	0.0043 (8)	0.0017 (7)	−0.0026 (8)
C4	0.0226 (10)	0.0243 (11)	0.0253 (11)	−0.0011 (8)	0.0033 (8)	−0.0077 (9)
C5	0.0290 (12)	0.0286 (12)	0.0331 (12)	−0.0038 (9)	0.0116 (10)	0.0025 (10)
C6	0.0342 (12)	0.0360 (13)	0.0222 (10)	0.0064 (10)	0.0106 (9)	0.0013 (10)
C7	0.0207 (10)	0.0222 (10)	0.0234 (10)	0.0011 (8)	0.0059 (8)	−0.0040 (9)

Geometric parameters (Å, º) top

Zn1—O5ⁱ	1.8791 (16)	O7—H7	0.8201
Zn1—O2	1.9121 (15)	N1—C7	1.329 (3)
Zn1—O4ⁱⁱ	1.9243 (15)	N1—C6	1.330 (3)
Zn1—O1ⁱⁱ	1.9888 (15)	N1—H1	0.8600
P1—O2	1.4907 (15)	C1—C2	1.542 (3)
P1—O1	1.5182 (15)	C2—C3	1.504 (3)
P1—O3	1.5594 (16)	C2—H2A	0.9700
P1—C1	1.843 (2)	C2—H2B	0.9700
P2—O6	1.4953 (15)	C3—C7	1.370 (3)
P2—O5	1.5115 (16)	C3—C4	1.380 (3)
P2—O4	1.5236 (15)	C4—C5	1.373 (3)
P2—C1	1.851 (2)	C4—H4A	0.9300
O1—Zn1ⁱⁱⁱ	1.9888 (15)	C5—C6	1.366 (3)
O3—H3	0.8200	C5—H5A	0.9300
O4—Zn1ⁱⁱⁱ	1.9243 (15)	C6—H6A	0.9300
O5—Zn1ⁱ	1.8791 (16)	C7—H7A	0.9300
O7—C1	1.424 (2)

O5ⁱ—Zn1—O2	106.21 (7)	O7—C1—C2	106.72 (16)
O5ⁱ—Zn1—O4ⁱⁱ	114.36 (7)	O7—C1—P1	107.57 (13)
O2—Zn1—O4ⁱⁱ	113.44 (6)	C2—C1—P1	109.45 (13)
O5ⁱ—Zn1—O1ⁱⁱ	117.63 (7)	O7—C1—P2	110.31 (13)
O2—Zn1—O1ⁱⁱ	106.02 (7)	C2—C1—P2	111.50 (14)
O4ⁱⁱ—Zn1—O1ⁱⁱ	99.08 (6)	P1—C1—P2	111.12 (10)
O2—P1—O1	112.93 (9)	C3—C2—C1	113.26 (16)
O2—P1—O3	110.75 (9)	C3—C2—H2A	108.9
O1—P1—O3	109.18 (9)	C1—C2—H2A	108.9
O2—P1—C1	111.10 (9)	C3—C2—H2B	108.9
O1—P1—C1	109.71 (9)	C1—C2—H2B	108.9
O3—P1—C1	102.68 (9)	H2A—C2—H2B	107.7
O6—P2—O5	112.64 (10)	C7—C3—C4	117.04 (19)
O6—P2—O4	111.29 (9)	C7—C3—C2	121.41 (19)
O5—P2—O4	113.84 (9)	C4—C3—C2	121.53 (19)
O6—P2—C1	108.04 (9)	C5—C4—C3	121.4 (2)
O5—P2—C1	103.62 (9)	C5—C4—H4A	119.3
O4—P2—C1	106.78 (9)	C3—C4—H4A	119.3
P1—O1—Zn1ⁱⁱⁱ	128.06 (8)	C6—C5—C4	118.6 (2)
P1—O2—Zn1	144.97 (10)	C6—C5—H5A	120.7
P1—O3—H3	109.5	C4—C5—H5A	120.7
P2—O4—Zn1ⁱⁱⁱ	123.97 (9)	N1—C6—C5	119.7 (2)
P2—O5—Zn1ⁱ	143.43 (10)	N1—C6—H6A	120.2
C1—O7—H7	109.4	C5—C6—H6A	120.2
C7—N1—C6	122.4 (2)	N1—C7—C3	120.9 (2)
C7—N1—H1	118.8	N1—C7—H7A	119.6
C6—N1—H1	118.8	C3—C7—H7A	119.6

Symmetry codes: (i) −x+1, −y+1, −z+1; (ii) x, y−1, z; (iii) x, y+1, z.

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
O3—H3···O1^iv	0.82	1.85	2.637 (2)	161
N1—H1···O6^v	0.86	1.68	2.533 (2)	170
O7—H7···O4ⁱⁱ	0.82	1.97	2.758 (2)	163

Symmetry codes: (ii) x, y−1, z; (iv) −x+1/2, y−1/2, −z+1/2; (v) −x+1/2, y+1/2, −z+3/2.

Experimental details

Crystal data
Chemical formula	[Zn(C₇H₉NO₇P₂)]
M_r	346.46
Crystal system, space group	Monoclinic, P2₁/n
Temperature (K)	293
a, b, c (Å)	13.609 (3), 5.4809 (11), 14.818 (3)
β (°)	101.21 (3)
V (Å³)	1084.2 (4)
Z	4
Radiation type	Mo Kα
µ (mm⁻¹)	2.59
Crystal size (mm)	0.20 × 0.12 × 0.08

Data collection
Diffractometer	Rigaku Mercury CCD area-detector diffractometer
Absorption correction	Multi-scan (RAPID-AUTO; Rigaku, 1998)
T_min, T_max	0.626, 0.820
No. of measured, independent and observed [I > 2σ(I)] reflections	8250, 2519, 2473
R_int	0.025
(sin θ/λ)_max (Å⁻¹)	0.654

Refinement
R[F² > 2σ(F²)], wR(F²), S	0.026, 0.061, 1.04
No. of reflections	2519
No. of parameters	163
H-atom treatment	H-atom parameters constrained
Δρ_max, Δρ_min (e Å⁻³)	0.35, −0.32

Computer programs: CrystalClear (Rigaku, 2002), SHELXS97 (Sheldrick, 2008), SHELXL97 (Sheldrick, 2008), SHELXTL/PC (Sheldrick, 2008).

Selected bond lengths (Å) top

Zn1—O5ⁱ	1.8791 (16)	P1—O3	1.5594 (16)
Zn1—O2	1.9121 (15)	P1—C1	1.843 (2)
Zn1—O4ⁱⁱ	1.9243 (15)	P2—O6	1.4953 (15)
Zn1—O1ⁱⁱ	1.9888 (15)	P2—O5	1.5115 (16)
P1—O2	1.4907 (15)	P2—O4	1.5236 (15)
P1—O1	1.5182 (15)	P2—C1	1.851 (2)

Symmetry codes: (i) −x+1, −y+1, −z+1; (ii) x, y−1, z.

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
O3—H3···O1ⁱⁱⁱ	0.82	1.85	2.637 (2)	161.1
N1—H1···O6^iv	0.86	1.68	2.533 (2)	169.6
O7—H7···O4ⁱⁱ	0.82	1.97	2.758 (2)	162.5

Symmetry codes: (ii) x, y−1, z; (iii) −x+1/2, y−1/2, −z+1/2; (iv) −x+1/2, y+1/2, −z+3/2.

Acknowledgements

This work was supported by the Innovation Fund for Young Scientist of Fujian Province (2008 F3059) and Fuzhou University (XRC0645, 2007-XQ-09).

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