Acta Cryst. (2010). E66, m46-m47 [ doi:10.1107/S1600536809052763 ]
Abstract: The crystal structure of the title compound, [Co(CO3)(C12H8N2)2]NO3·H2O, consists of CoIII complex cations, nitrate anions and uncoordinated water molecules. The CoIII cation is chelated by a carbonate anion and two phenanthroline ligands in a distorted octahedral coordination geometry. A three-dimensional supramolecular structure is formed by O-HO and C-HO hydrogen bonding, C-H and aromatic - stacking [centroid-centroid distance = 3.995 (1)Å] interactions.
Online 12 December 2009
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