Acta Cryst. (2010). E66, m142-m143 [ doi:10.1107/S1600536810000073 ]
Abstract: There are two monomeric units in the asymmetric unit of the polymeric title compound, [Na(C5H4NOS)(C10H8N2O2S2)(H2O)]n. The NaI ions are six coordinated by four O atoms, one S atom and one water molecule, forming a slightly distorted octahedral geometry. An intramolecular O-HO hydrogen bond stabilizes the conformation of the molecule. The crystal packing is consolidated by intermolecular O-HO, O-HN and O-HS hydrogen bonds, - interactions [with centroid-centroid distances of 3.587 (2) Å] together with weak C-H interactions. The molecules are linked into polymeric chains along the b-axis direction.
Online 13 January 2010
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