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Acta Cryst. (2010). E66, m200  [ doi:10.1107/S1600536810002485 ]

Diacridinium tetrakis(thiocyanato-[kappa]S)platinate(II)

K. Ha

Abstract: The asymmetric unit of the title compound, (C13H10N)2[Pt(NCS)4], contains a protonated acridine molecule and one half of a [Pt(NCS)4]2- anion. In the complex anion, the PtII ion is located on an inversion centre and is four-coordinated in a slightly distorted square-planar environment by four S atoms from four thiocyanate ligands. The compound displays numerous intermolecular [pi]-[pi] interactions between six-membered rings, with a shortest centroid-centroid distance of 3.682 (3) Å. The component ions interact by means of intermolecular N-H...N hydrogen bonds.

Online 23 January 2010


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